Ternary mixtures of ionic liquids for better salt solubility, conductivity and cation transference number improvement

Ewelina Karpierz , Leszek Niedzicki , Tomasz Trzeciak , Maciej Zawadzki , Maciej Dranka , Janusz Zachara , Grażyna Żukowska , Anna Bitner-Michalska , Władysław Wieczorek

Abstract

We hereby present the new class of ionic liquid systems in which lithium salt is introduced into the solution as a lithium cation−glyme solvate. This modification leads to the reorganisation of solution structure, which entails release of free mobile lithium cation solvate and hence leads to the significant enhancement of ionic conductivity and lithium cation transference numbers. This new approach in composing electrolytes also enables even three-fold increase of salt concentration in ionic liquids.
Author Ewelina Karpierz KChNTCS
Ewelina Karpierz,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Leszek Niedzicki KChNTCS
Leszek Niedzicki,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Tomasz Trzeciak KChNTCS
Tomasz Trzeciak,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Maciej Zawadzki ZChF
Maciej Zawadzki,,
- Department Of Physical Chemistry
, Maciej Dranka KChNTCS
Maciej Dranka,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Janusz Zachara KChNTCS
Janusz Zachara,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Grażyna Żukowska KChNTCS
Grażyna Żukowska,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Anna Bitner-Michalska KChNTCS
Anna Bitner-Michalska,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Władysław Wieczorek KChNTCS
Władysław Wieczorek,,
- Chair Of Inorganic Chemistry And Solid State Technology
Journal seriesScientific Reports, ISSN 2045-2322
Issue year2016
Vol6
Pages1-8
Publication size in sheets0.5
DOIDOI:10.1038/srep35587
URL http://www.nature.com/articles/srep35587
Languageen angielski
File
srep35587.pdf 778.92 KB
Score (nominal)40
ScoreMinisterial score [Punktacja MNiSW] = 40.0, 28-11-2017, ArticleFromJournal
Ministerial score (2013-2016) [Punktacja MNiSW (2013-2016)] = 40.0, 28-11-2017, ArticleFromJournal
Publication indicators WoS Impact Factor [Impact Factor WoS]: 2016 = 4.259 (2) - 2016=4.847 (5)
Citation count*0
Cite
Share Share

Get link to the record
msginfo.png


* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
Back