Structural disorder in Lix(C5H5N)yFe2-zSe2 and CsxFe2-zSe2 superconductors studied by Mössbauer spectroscopy

K. Komędera , A.K. Jasek , A. Błachowski , K. Ruebenbauer , J. Żukrowski , Anna Krztoń-Maziopa , K. Conder

Abstract

Two iron-chalcogenide superconductors Lix(C5H5N)yFe2−zSe2 and CsxFe2–zSe2 in the as-prepared and annealed state have been investigated by means of the Mössbauer spectroscopy versus temperature. Multi-component spectra are obtained. One can see a non-magnetic component due to iron located in the unperturbed Fe–Se sheets responsible for superconductivity. Remaining components are magnetically ordered even at room temperature. There is some magnetically ordered iron in Fe–Se sheets perturbed by presence of the iron vacancies. Additionally, one can see iron dispersed between sheets in the form of magnetically ordered high spin trivalent ions, some clusters of above ions, and in the case of pyridine intercalated compound in the form of α-Fe precipitates. Pyridine intercalated sample shows traces of superconductivity in the as-prepared state, while cesium intercalated sample in the as-prepared state does not show any superconductivity. Superconductors with transition temperatures being 40 K and 25 K, respectively, are obtained upon annealing. Annealing leads to removal/ordering of the iron vacancies within Fe–Se sheets, while clusters of α-Fe grow in the pyridine intercalated sample.
Author K. Komędera - [Uniwersytet Pedagogiczny im. Komisji Edukacji Narodowej]
K. Komędera,,
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, A.K. Jasek - [Uniwersytet Pedagogiczny im. Komisji Edukacji Narodowej]
A.K. Jasek,,
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, A. Błachowski - [Uniwersytet Pedagogiczny im. Komisji Edukacji Narodowej]
A. Błachowski,,
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, K. Ruebenbauer - [Uniwersytet Pedagogiczny im. Komisji Edukacji Narodowej]
K. Ruebenbauer,,
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, J. Żukrowski - [AGH University of Science and Technology (AGH)]
J. Żukrowski,,
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- Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie
, Anna Krztoń-Maziopa (FC / CICSST)
Anna Krztoń-Maziopa,,
- Chair Of Inorganic Chemistry And Solid State Technology
, K. Conder - [Paul Scherrer Institut]
K. Conder,,
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Journal seriesJournal of Magnetism and Magnetic Materials, ISSN 0304-8853
Issue year2016
Vol406
Pages244-250
Publication size in sheets0.5
Keywords in EnglishIron chalcogenides; Intercalation; Mössbauer spectroscopy
ASJC Classification3104 Condensed Matter Physics; 2504 Electronic, Optical and Magnetic Materials
DOIDOI:10.1016/j.jmmm.2016.01.003
URL http://www.sciencedirect.com/science/article/pii/S0304885316300051
Languageen angielski
File
1-s2.0-S0304885316300051-main.pdf 1.41 MB
Score (nominal)30
Score sourcejournalList
ScoreMinisterial score = 30.0, 07-01-2020, ArticleFromJournal
Ministerial score (2013-2016) = 30.0, 07-01-2020, ArticleFromJournal
Publication indicators Scopus Citations = 3; WoS Citations = 2; Scopus SNIP (Source Normalised Impact per Paper): 2016 = 1.172; WoS Impact Factor: 2016 = 2.63 (2) - 2016=2.36 (5)
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