Cu-Fe-S Nanocrystals Exhibiting Tunable Localized Surface Plasmon Resonance in the Visible to NIR Spectral Ranges
Grzegorz Gąbka , Piotr Bujak , Andrzej Ostrowski , Waldemar Tomaszewski , Wojciech Lisowski , Janusz Sobczak , Adam Proń
AbstractCu–Fe–S nanocrystals exhibiting a strong localized surface plasmon resonance (LSPR) effect were synthesized for the first time. The elaborated reproducible preparation procedure involved copper(II) oleate, iron(III) stearate, and sulfur powder dissolved in oleylamine (OLA) as precursors. The wavelength of the plasmonic resonance maximum could be tuned by changing the Cu/Fe ratio in the resulting nanocrystals, being the most energetic for the 1:1 ratio (486 nm) and undergoing a bathochromic shift to ca. 1200 nm with an increase to 6:1. LSPR could also be observed in nanocrystals prepared from the same metal precursors and sulfur powder dissolved in 1-octadecene (ODE), provided that the sulfur precursor was taken in excess. Detailed analysis of the reaction mixture by chromatographic techniques, supplemented by mass spectrometry and 1H NMR spectroscopy enabled the identification of the true chemical nature of the sulfur precursor in S/OLA, namely, (C18H35NH3+)(C18H35NH–S8–), a reactive product of the reduction of elemental sulfur by the amine groups of OLA. In the case of the S/ODE precursor, the true precursors are much less reactive primary or secondary thioethers and dialkyl polysulfides.
|Journal series||Inorganic Chemistry, ISSN 0020-1669|
|Publication size in sheets||0.5|
|Score|| = 40.0, 28-11-2017, ArticleFromJournal|
= 45.0, 28-11-2017, ArticleFromJournal
|Publication indicators||: 2016 = 4.857 (2) - 2016=4.503 (5)|
|Citation count*||10 (2018-07-17)|
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.