Preparation and enhanced mechanical properties of hydroxyapatite hybrid hydrogels via novel photocatalytic polymerization

Da-Jhan Chiu , Ying Li , Chi-Kuang Feng , Mu-Rong Yang , Ko-Shao Chen , Wojciech Święszkowski

Abstract

Hydroxyapatite (HA) hybridized poly(N-isopropylacrylamide)-co-acrylic acid (PNIPAM-co-AAc) hydrogel on thermoplastic polyurethane (TPU) were successfully prepared via photocatalytic polymerization technique. Low temperature plasma processing of HMDSZ and O2 plasma were deposition on substrate. The HA/hydrogel were stabilized by HA of which the wettability was modified by calcium nitrate and ammonium phosphate dibasic. The HA gradually increases with the increase of time cycles. The deposition of organic silicone group by the HMDSZ on the TPU substrate is hydrophobic surface. When deposition of O2, the water contact angles (WCA) was changed to <10° and surface hydrophilicity. The materials were characterized by OM, SEM, FT-IR, XPS and XRD. The results showed that the NIPAM: AAc (1:1 mol) polymers possess macropores ranging from 2 to 20 μm, and their large numbers of carboxyl groups and hydroxyl groups result in a favorable adsorption capacity for HA. Swelling studies indicated that NIPAM: AAc (1:1 mol) was 446 ± 0.3%. This work provided a promising alternative method for the fabrication of polymer materials with tunable and interconnected pores structures for the HA.
Author Da-Jhan Chiu - Tatung University, Taiwan [Tatung University]
Da-Jhan Chiu,,
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, Ying Li - Ming Chi University of Technology, Taipei, Taiwan [Mingchi Institute of Technology]
Ying Li,,
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, Chi-Kuang Feng - Veterans General Hospital-Taipei, Taipei, Taiwan [Veterans General Hospital-Taipei]
Chi-Kuang Feng,,
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, Mu-Rong Yang - Tatung University, Taiwan [Tatung University]
Mu-Rong Yang,,
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, Ko-Shao Chen - Ming Chi University of Technology, Taipei, Taiwan [Tatung University]
Ko-Shao Chen,,
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, Wojciech Święszkowski (FMSE / DMD)
Wojciech Święszkowski,,
- Division of Materials Design
Journal seriesJournal of Polymer Research, ISSN 1022-9760, (A 30 pkt)
Issue year2018
Vol24
No12
Pages227-235
Publication size in sheets0.5
Keywords in EnglishLow temperature plasma, Photocatalytic polymerization, Composite hydrogel, Hydroxyapatite
ASJC Classification2505 Materials Chemistry; 1605 Organic Chemistry; 2507 Polymers and Plastics
DOIDOI:10.1007/s10965-017-1382-5
URL https://doi.org/10.1007/s10965-017-1382-5
Languageen angielski
File
10.1007s10965-017-1382-5.pdf 4.45 MB
Score (nominal)30
ScoreMinisterial score = 30.0, 14-02-2018, ArticleFromJournal
Ministerial score (2013-2016) = 30.0, 14-02-2018, ArticleFromJournal
Publication indicators Scopus SNIP (Source Normalised Impact per Paper): 2017 = 0.52; WoS Impact Factor: 2017 = 1.434 (2) - 2017=1.636 (5); Scopus Citations = 3; WoS Citations = 2
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