(Vapor + liquid) phase equilibria of an aqueous solution of bromide-based ionic liquids – measurements, correlations and application to absorption cycles

Marta Królikowska , Kamil Paduszyński , Maciej Zawadzki


In this work, thermodynamic and physicochemical properties including (vapor + liquid) equilibria (VLE), density and dynamic viscosity of binary mixtures composed of bromide-based ionic liquid (IL) and water were measured as a function of IL mole fraction in a wide range of temperature. The aqueous solution of the following ILs: 1-ethyl-1-methylpiperidinium bromide, ethylpyridinium bromide, 1-(2-hydroxyethyl)pyridinium bromide, 1-ethyl-1-methyl-morpholinium bromide, 1-hydroxyethyl-1-methylmorpholinium bromide, and N-ethyl-N,N-dimethyl-N-hydroxyethylammonium bromide have been tested for potential applications as working fluids in absorption refrigeration technology. The isothermal VLE has been measured by an ebulliometric method within a temperature range from T = (338.15–368.15) K and pressure up to 85 kPa and correlated using Redlich-Kwong equation of state. This work is a continuation of our systematic investigation of an aqueous solution of ionic liquids as a potential working fluid in absorption refrigeration technology. The summary of this research is the modeling of the theoretical cycles using working fluids proposed in this paper. The calculated values of the coefficient of performance (COP) were compared to other ILs from available literature and {LiBr + water} system, conventionally used on the industrial scale in absorption refrigeration technology.
Author Marta Królikowska (FC / DPC)
Marta Królikowska,,
- Department Of Physical Chemistry
, Kamil Paduszyński (FC / DPC)
Kamil Paduszyński,,
- Department Of Physical Chemistry
, Maciej Zawadzki (FC / DPC)
Maciej Zawadzki,,
- Department Of Physical Chemistry
Journal seriesFluid Phase Equilibria, ISSN 0378-3812
Issue year2019
Publication size in sheets0.5
Keywords in EnglishIonic liquidWaterVLEDensityViscosityCoefficient of performanceModeling
ASJC Classification16 Chemistry
URL https://www.sciencedirect.com/science/article/pii/S0378381219302110?via%3Dihub
Languageen angielski
1-s2.0-S0378381219302110-main.pdf 1.36 MB
Score (nominal)100
Score sourcejournalList
ScoreMinisterial score = 100.0, 03-02-2020, ArticleFromJournal
Publication indicators Scopus Citations = 1; WoS Citations = 0; Scopus SNIP (Source Normalised Impact per Paper): 2017 = 1.033; WoS Impact Factor: 2018 = 2.514 (2) - 2018=2.28 (5)
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