Bis(cyclic carbonate) based on D-mannitol, D-sorbitol and di(trimethylolpropane) in the synthesis of non-isocyanate poly(carbonate-urethane)s

Gabriel Rokicki , Magdalena Mazurek , Mateusz Drzewicz , Piotr Guńka , Janusz Zachara

Abstract

Bis(cyclic carbonate)s based on sugar alcohols such as D-mannitol, D-sorbitol as well as di(trimethylolpropane) were used as monomers for preparation of a variety of crosslinked poly(carbonate-urethane)s (PCUs), which do not require either phosgene or toxic isocyanate monomers. In the approach proposed by us, crosslinked structure of poly(carbonate-urethane)s are obtained in the reaction of amine-terminated oligo(hydroxy-urethane)s with six-membered bis(cyclic carbonate) and then by polymerization of residual six-membered cyclic carbonate ending groups. Depending on the aliphatic diamine used as well as the molar ratio of five- to six-membered bis(cyclic carbonate)s the obtained non-isocyanates polyurethanes (NIPUs) were characterized by elastomeric or rigid properties.
Author Gabriel Rokicki KChTP
Gabriel Rokicki,,
- Chair Of Polymer Chemistry And Technology
, Magdalena Mazurek KChTP
Magdalena Mazurek,,
- Chair Of Polymer Chemistry And Technology
, Mateusz Drzewicz KChTP
Mateusz Drzewicz,,
- Chair Of Polymer Chemistry And Technology
, Piotr Guńka KChNTCS
Piotr Guńka,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Janusz Zachara KChNTCS
Janusz Zachara,,
- Chair Of Inorganic Chemistry And Solid State Technology
Journal seriesEuropean Polymer Journal, ISSN 0014-3057
Issue year2016
Vol84
Pages799-811
Publication size in sheets0.6
Keywords in EnglishBis(cyclic carbonate)s based on D-mannitol and D-sorbitol; Non-isocyanate polyurethane; Poly(carbonate-urethane) thermoset
DOIDOI:10.1016/j.eurpolymj.2016.04.021
URL https://www.scopus.com/record/display.uri?eid=2-s2.0-84965075911&origin=resultslist&sort=plf-f&src=s&sid=9CC051C4905924200BEBDD6560B524CE.wsnAw8kcdt7IPYLO0V48gA%3a820&sot=autdocs&sdt=autdocs&sl=17&s=AU-ID%287003780818%29&relpos=0&citeCnt=0&searchTerm=
Languageen angielski
File
wdpb_publikacje_pliki_plik_publikacja_3017_org.pdf 1.08 MB
Score (nominal)35
ScoreMinisterial score = 35.0, 28-11-2017, ArticleFromJournal
Ministerial score (2013-2016) = 35.0, 28-11-2017, ArticleFromJournal
Publication indicators WoS Impact Factor: 2016 = 3.531 (2) - 2016=3.658 (5)
Citation count*0
Cite
Share Share

Get link to the record
msginfo.png


* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
Back