Bis(cyclic carbonate) based on D-mannitol, D-sorbitol and di(trimethylolpropane) in the synthesis of non-isocyanate poly(carbonate-urethane)s
Gabriel Rokicki , Magdalena Mazurek , Mateusz Drzewicz , Piotr Guńka , Janusz Zachara
AbstractBis(cyclic carbonate)s based on sugar alcohols such as D-mannitol, D-sorbitol as well as di(trimethylolpropane) were used as monomers for preparation of a variety of crosslinked poly(carbonate-urethane)s (PCUs), which do not require either phosgene or toxic isocyanate monomers. In the approach proposed by us, crosslinked structure of poly(carbonate-urethane)s are obtained in the reaction of amine-terminated oligo(hydroxy-urethane)s with six-membered bis(cyclic carbonate) and then by polymerization of residual six-membered cyclic carbonate ending groups. Depending on the aliphatic diamine used as well as the molar ratio of five- to six-membered bis(cyclic carbonate)s the obtained non-isocyanates polyurethanes (NIPUs) were characterized by elastomeric or rigid properties.
|Journal series||European Polymer Journal, ISSN 0014-3057|
|Publication size in sheets||0.6|
|Keywords in English||Bis(cyclic carbonate)s based on D-mannitol and D-sorbitol; Non-isocyanate polyurethane; Poly(carbonate-urethane) thermoset|
|ASJC Classification||; ;|
|Score|| = 35.0, 02-02-2020, ArticleFromJournal|
= 35.0, 02-02-2020, ArticleFromJournal
|Publication indicators||= 17; = 19; : 2016 = 1.303; : 2016 = 3.531 (2) - 2016=3.658 (5)|
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