Mechano-insertion syntheses of molybdate silver ion conductors: Process traits and driving factors

Paweł Grabowski , Jan Nowiński , P. Kamińska


In this work we present traits of mechano-inserion technique employed in a formation process of AgI-Ag2O-MoO3 ion conductors. Our methodology adopted incorporation of external AgI amounts into ahead formed molybdate silver ion conducting glasses by means of ball-milling method. The primary glasses were formed using rapid quenching techniques with applied different cooling rates. The final synthesis of both components resulted in formation of new products: homogeneous or heterogeneous. We discuss the principles governing in the synthesis course in terms of processing method and starting materials. Correlation of XRD and MDSC results points to central factors driving the mechano-insertion process: alongside of mechanosynthesis parameters, the target chemical composition and structure of primary glass precondition the properties of yielded products. © 2016 Elsevier B.V.
Author Paweł Grabowski (FP / SSID)
Paweł Grabowski,,
- Solid State Ionics Division
, Jan Nowiński (FP / SSID)
Jan Nowiński,,
- Solid State Ionics Division
, P. Kamińska
P. Kamińska,,
Journal seriesJournal of Non-Crystalline Solids, ISSN 0022-3093
Issue year2016
Publication size in sheets0.5
Keywords in EnglishBall milling; Ions; Metal ions; Molybdenum oxide; Silver halides, Glass formation; Mdsc; Mechano-insertion; Mechanosynthesis; Silver iodide; Superionic glass, Glass
Languageen angielski
Score (nominal)30
ScoreMinisterial score = 30.0, 28-11-2017, ArticleFromJournal
Ministerial score (2013-2016) = 30.0, 28-11-2017, ArticleFromJournal
Publication indicators WoS Impact Factor: 2016 = 2.124 (2) - 2016=1.926 (5)
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