Back
Katalityczne utlenianie w fazie ciekłej etylobenzenu ozonem w lodowatym kwasie octowym
Authors:
- A. Galstyan,
- O. Marshalok,
- G. Galstyan,
- Halyna Marshalok
Abstract
The kinetics of PhEt oxidation with an O3-air mixture in glacial AcOH in presence of Mn(OAc)2 was studied. Introduction of the catalyst resulted in an increase of the side-chain oxidation selectivity from 34.0 to 83.7%. AcPh (76.0%) and PhMeCHOAc (9.7%) were the main reaction products. Traces of PhMeCHOH and PhCHO were found in the reaction mixt. No products of PhH ring ozonolysis were detected.
- Record ID
- WUTb9ba297813f54a3db1cbcedccebdfcd2
- Author
- Other language title versions
- Liquid-phase catalytic oxidation of ethylbenzene with ozone in glacial acetic acid
- Journal series
- Przemysł Chemiczny, ISSN 0033-2496
- Issue year
- 2020
- Vol
- 99
- No
- 2
- Pages
- 308-312
- Publication size in sheets
- 0.50
- Keywords in Polish
- Etylobenzen, utlenianie, ozon
- Keywords in English
- Ethylbenzene, oxidation, ozone
- ASJC Classification
- ;
- Abstract in Polish
- Zbadano kinetykę utleniania etylobenzenu mieszaniną ozonowo-powietrzną w lodowatym kwasie octowym. Wprowadzenie octanu manganu(II) jako katalizatora do układu reakcyjnego zwiększyło selektywność utleniania łańcucha bocznego z 34,0% do 83,7%. Głównym produktem reakcji był acetofenon (76,0%) i octan metylofenylokarbinolu (9,7%).
- DOI
- DOI:10.15199/62.2020.2.23 Opening in a new tab
- Language
- (pl) Polish
- Score (nominal)
- 70
- Score source
- journalList
- Score
- = 70.0, 21-12-2021, ArticleFromJournal
- Publication indicators
- = 0; : 2016 = 0.203; : 2019 (2 years) = 0.485 - 2019 (5 years) =0.405
Share
- Uniform Resource Identifier
- https://repo.pw.edu.pl/info/article/WUTb9ba297813f54a3db1cbcedccebdfcd2/
- URN
urn:pw-repo:WUTb9ba297813f54a3db1cbcedccebdfcd2
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.