Modeling of ozone reaction with benzaldehyde incorporating ozone decomposition in aqueous solutions
Andrzej Konrad Biń , Piotr M. Machniewski , Jolanta Wołyniec , Agata Pieńczakowska
AbstractOzonation of benzaldehyde in its aqueous solutions based on mechanistic approach and incorporating ozone decomposition model is presented in this work. As the basis the modified and extended HSB model of ozone decomposition with phosphates and carbonates reactions included has been applied. It was then tuned with the literature data and the results of our own measurements on ozone decay in aqueous solutions. The model was extended to model benzaldehyde oxidation reactions in the aqueous solutions. Model predictions compare favorably against experimental data obtained in the range of pH 2.3 to 8 with or without radical scavenger (t-butanol).
|Journal series||Ozone: Science & Engineering: The Journal of the International Ozone Association, ISSN 0191-9512|
|Publication size in sheets||0.55|
|Keywords in English||ozone, benzaldehyde, decomposition, VOC oxidation, numerical simulation|
|Score|| = 15.0, 18-05-2020, ArticleFromJournal|
= 20.0, 18-05-2020, ArticleFromJournal
|Publication indicators||= 4; = 1.0; : 2013 = 0.708; : 2013 = 0.954 (2) - 2013=1.109 (5)|
|Citation count*||1 (2015-02-14)|
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.