Optimization of methylalumoxane based composite polymeric electrolytes for lithium battery applications

Michał Piszcz , Maciej Marczewski , Grażyna Żukowska , J. Wójcik , Władysław Wieczorek , Maciej Siekierski

Abstract

Composite polymer electrolytes are developed towards nanosized fillers to improve electrochemical properties upon the decrease of the size of the filler grain. Further improvement can be achieved by means of chemical incorporation of the inorganic part into the polymeric backbone. By these means both branched and crosslinked structures can be achieved with strict control of crosslink density. The paper presented shows the possibilities of tailoring the properties of organic–inorganic composite towards its application in lithium batteries. The increase of conductivity has been proved together with the improvement of material homogeneity, lack of crystallization, improved thermal stability of the electrolyte and improved salt dissociation, efficient stabilization of lithium-CPE SEI and promising cycling properties.
Author Michał Piszcz (FC / CICSST)
Michał Piszcz,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Maciej Marczewski (FC / CICSST)
Maciej Marczewski,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Grażyna Żukowska (FC / CICSST)
Grażyna Żukowska,,
- Chair Of Inorganic Chemistry And Solid State Technology
, J. Wójcik (FC / CICSST)
J. Wójcik,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Władysław Wieczorek (FC / CICSST)
Władysław Wieczorek,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Maciej Siekierski (FC / CICSST)
Maciej Siekierski,,
- Chair Of Inorganic Chemistry And Solid State Technology
Journal seriesSolid State Ionics, ISSN 0167-2738
Issue year2013
Vol245-246
Pages33-42
Publication size in sheets0.5
Keywords in EnglishLithium battery, Organic–inorganic system, Composite polymeric electrolyte, TG-FTIR, Vibrational spectroscopy
ASJC Classification3104 Condensed Matter Physics; 2500 General Materials Science; 1600 General Chemistry
DOIDOI:10.1016/j.ssi.2013.04.015
URL http://www.sciencedirect.com/science/article/pii/S0167273813002178
Languageen angielski
File
1-s2.0-S0167273813002178-main.pdf 1.14 MB
Score (nominal)35
Score sourcejournalList
ScoreMinisterial score = 30.0, 05-04-2020, ArticleFromJournal
Ministerial score (2013-2016) = 35.0, 05-04-2020, ArticleFromJournal
Publication indicators Scopus Citations = 3; WoS Citations = 3; GS Citations = 1.0; Scopus SNIP (Source Normalised Impact per Paper): 2013 = 1.269; WoS Impact Factor: 2013 = 2.112 (2) - 2013=2.397 (5)
Citation count*1 (2016-03-19)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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