Optimization of methylalumoxane based composite polymeric electrolytes for lithium battery applications
Michał Piszcz , Maciej Marczewski , Grażyna Żukowska , J. Wójcik , Władysław Wieczorek , Maciej Siekierski
AbstractComposite polymer electrolytes are developed towards nanosized fillers to improve electrochemical properties upon the decrease of the size of the filler grain. Further improvement can be achieved by means of chemical incorporation of the inorganic part into the polymeric backbone. By these means both branched and crosslinked structures can be achieved with strict control of crosslink density. The paper presented shows the possibilities of tailoring the properties of organic–inorganic composite towards its application in lithium batteries. The increase of conductivity has been proved together with the improvement of material homogeneity, lack of crystallization, improved thermal stability of the electrolyte and improved salt dissociation, efficient stabilization of lithium-CPE SEI and promising cycling properties.
|Journal series||Solid State Ionics, ISSN 0167-2738|
|Publication size in sheets||0.5|
|Keywords in English||Lithium battery, Organic–inorganic system, Composite polymeric electrolyte, TG-FTIR, Vibrational spectroscopy|
|ASJC Classification||; ;|
|Score|| = 30.0, 05-04-2020, ArticleFromJournal|
= 35.0, 05-04-2020, ArticleFromJournal
|Publication indicators||= 3; = 3; = 1.0; : 2013 = 1.269; : 2013 = 2.112 (2) - 2013=2.397 (5)|
|Citation count*||1 (2016-03-19)|
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.