Quest for efficient catalysts based on zinc tert-butylperoxides for asymmetric epoxidation of enones: C2– vs C1–Symmetric auxiliaries
Abdul Raheem Keeri , Iwona Justyniak , Janusz Jurczak , Janusz Lewiński
AbstractZinc tert-butyl peroxide-based catalysts for the asymmetric epoxidation of enones using tert-butyl hydroperoxide as an oxidant have been developed. A comparative study of chiral monoanioninc N,N′-bidentate ligands, C2-symmetric bisoxazolinates and C1-symmetric enaminooxazolinates, revealed excellent performance of C1-symmetric auxiliary ligands on catalytic asymmetric epoxidation of enones (up to 96% yield, 91% ee).
|Journal series||Advanced Synthesis & Catalysis, ISSN 1615-4150|
|Publication size in sheets||0.5|
|Keywords in English||asymmetric catalysis;chiral auxiliaries;epoxidation of enones;ligand design;zinc|
|Score|| = 45.0, 31-01-2020, ArticleFromJournal|
= 45.0, 31-01-2020, ArticleFromJournal
|Publication indicators||= 12; = 8; : 2016 = 0.959; : 2016 = 5.646 (2) - 2016=5.229 (5)|
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