Magnetic field alignment in highly concentrated suspensions for gelcasting process

Agnieszka Szudarska , Yoshio Sakka , Tohru S. Suzuki , Tadeusz Mizerski , Mikołaj Szafran

Abstract

The aim of the current paper is to present the development of the method used for fabricating highly textured α-alumina elements. The experimental procedure described is based on a combination of two techniques: gelcasting is used in tandem with high magnetic field exposure. In the element shaping process, a new, low-toxic and environmentally friendly gelating system was implemented that is based on in situ polymerisation of an acryloyl derivative of galactose. Here, care was taken to achieve a highly textured structure of elements gelcast from the ceramic slurries of high solid contents (45–50 vol%), which have not been processed successfully for magnetic field alignment before. A secondary aim of the study was to investigate the combined effect of magnetic field exposure duration and the idle time of polymerisation on the effectiveness of the alignment. In the course of the experiment, high degrees of crystalline orientation of the gelcast samples were obtained ranging from 0.92 to 0.96, developed after the subsequent sintering at 1600 °C (the parameters were calculated on the basis of XRD pattern of the surface perpendicular to the magnetic field direction). The microstructures of the obtained elements are described in detail at the end of the paper, in a stereological analysis.
Author Agnieszka Szudarska KTCh
Agnieszka Szudarska,,
- Chair of Chemical Technology
, Yoshio Sakka
Yoshio Sakka,,
-
, Tohru S. Suzuki
Tohru S. Suzuki,,
-
, Tadeusz Mizerski ZChO
Tadeusz Mizerski,,
- Department Of Organic Chemistry
, Mikołaj Szafran KTCh
Mikołaj Szafran,,
- Chair of Chemical Technology
Journal seriesCeramics International, ISSN 0272-8842
Issue year2016
Vol42
No1, part A
Pages294-301
Publication size in sheets0.5
Keywords in EnglishShaping; Suspensions; Alumina; Texturisation
DOIDOI:10.1016/j.ceramint.2015.08.108
URL http://www.sciencedirect.com/science/article/pii/S0272884215016338
Languageen angielski
File
1-s2.0-S0272884215016338-main(1).pdf 2.4 MB
Score (nominal)40
ScoreMinisterial score = 40.0, 28-11-2017, ArticleFromJournal
Ministerial score (2013-2016) = 40.0, 28-11-2017, ArticleFromJournal
Publication indicators WoS Impact Factor: 2016 = 2.986 (2) - 2016=2.814 (5)
Citation count*1 (2016-05-30)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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