Magnetic field alignment in highly concentrated suspensions for gelcasting process

Agnieszka Szudarska , Yoshio Sakka , Tohru S. Suzuki , Tadeusz Mizerski , Mikołaj Szafran

Abstract

The aim of the current paper is to present the development of the method used for fabricating highly textured α-alumina elements. The experimental procedure described is based on a combination of two techniques: gelcasting is used in tandem with high magnetic field exposure. In the element shaping process, a new, low-toxic and environmentally friendly gelating system was implemented that is based on in situ polymerisation of an acryloyl derivative of galactose. Here, care was taken to achieve a highly textured structure of elements gelcast from the ceramic slurries of high solid contents (45–50 vol%), which have not been processed successfully for magnetic field alignment before. A secondary aim of the study was to investigate the combined effect of magnetic field exposure duration and the idle time of polymerisation on the effectiveness of the alignment. In the course of the experiment, high degrees of crystalline orientation of the gelcast samples were obtained ranging from 0.92 to 0.96, developed after the subsequent sintering at 1600 °C (the parameters were calculated on the basis of XRD pattern of the surface perpendicular to the magnetic field direction). The microstructures of the obtained elements are described in detail at the end of the paper, in a stereological analysis.
Author Agnieszka Szudarska (FC / CChT)
Agnieszka Szudarska,,
- Chair of Chemical Technology
, Yoshio Sakka
Yoshio Sakka,,
-
, Tohru S. Suzuki
Tohru S. Suzuki,,
-
, Tadeusz Mizerski (FC / DOC)
Tadeusz Mizerski,,
- Department Of Organic Chemistry
, Mikołaj Szafran (FC / CChT)
Mikołaj Szafran,,
- Chair of Chemical Technology
Journal seriesCeramics International, ISSN 0272-8842
Issue year2016
Vol42
No1, part A
Pages294-301
Publication size in sheets0.5
Keywords in EnglishShaping; Suspensions; Alumina; Texturisation
ASJC Classification2505 Materials Chemistry; 2508 Surfaces, Coatings and Films; 1508 Process Chemistry and Technology; 2503 Ceramics and Composites; 2504 Electronic, Optical and Magnetic Materials
DOIDOI:10.1016/j.ceramint.2015.08.108
URL http://www.sciencedirect.com/science/article/pii/S0272884215016338
Languageen angielski
File
1-s2.0-S0272884215016338-main(1).pdf 2.4 MB
Score (nominal)40
Score sourcejournalList
ScoreMinisterial score = 40.0, 10-01-2020, ArticleFromJournal
Ministerial score (2013-2016) = 40.0, 10-01-2020, ArticleFromJournal
Publication indicators GS Citations = 1.0; Scopus SNIP (Source Normalised Impact per Paper): 2016 = 1.382; WoS Impact Factor: 2016 = 2.986 (2) - 2016=2.814 (5)
Citation count*1 (2016-05-30)
Cite
Share Share

Get link to the record


* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
Back
Confirmation
Are you sure?