Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies
Pravas Deria , J. E. Mondloch , E. Tylianakis , P. Ghosh , Wojciech Bury , R. Q. Snurr , J. T. Hupp , O. K. Farha
AbstractA new functionalization technique, solvent-assisted ligand incorporation (SALI), was developed to efficiently incorporate carboxylate-based functionalities in the Zr-based metal–organic framework, NU-1000. Unlike previous metal node functionalization strategies, which utilize dative bonding to coordinatively unsaturated metal sites, SALI introduces functional groups as charge compensating and strongly bound moieties to the Zr6 node. Utilizing SALI, we have efficiently attached perfluoroalkane carboxylates of various chain lengths (C1–C9) on the Zr6 nodes of NU-1000. These fluoroalkane-functionalized mesoporous MOFs, termed herein SALI-n, were studied experimentally and theoretically as potential CO2 capture materials.
|Journal series||Journal of the American Chemical Society, ISSN 0002-7863|
|Publication size in sheets||0.5|
|Score|| = 40.0, 28-11-2017, ArticleFromJournal|
= 45.0, 28-11-2017, ArticleFromJournal
|Publication indicators||: 2013 = 11.444 (2) - 2013=11.015 (5)|
|Citation count*||41 (2015-06-01)|
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.