Metal substituted sulfonated poly(2,6-dimethyl-1,4-phenylene oxide) hybrid membranes with magnetic fillers for gas separation

Aleksandra Rybak , Aurelia Rybak , Waldemar Kaszuwara , Mariusz Nyc , Monika Auguścik

Abstract

Magnetic inorganic-organic hybrid membranes based on metal (Na+ and Fe2+) substituted sulfonated poly(2,6-dimethyl-1,4-phenylene oxide) matrix and magnetic powders were prepared and characterized. It was stated that the magnetic membrane's gas transport parameters (D, P, S and α) were improved with the rise of membrane's saturation magnetization, remanence, magnetic particle content and type of polymer matrix. The modification of a polymer matrix by metal substitution and incorporation of magnetic powder had significantly changed membrane's magnetic, mechanical (Rm and E) and rheological (G′ and G″) properties. Especially the introduction of Fe2+ ions (much higher magnetic susceptibility compared to Na+), and their potential interaction with magnetic powder resulted in improved properties. The mechanical and rheological parameters of the tested membranes were improved by the increase of the magnetic filler addition and selection of appropriate type of polymer matrix. The best resistance to elastic deformation had the hybrid FeSPPO membrane with high filler addition.

Author Aleksandra Rybak - Silesian University of Technology (PolSL)
Aleksandra Rybak,,
-
, Aurelia Rybak - Silesian University of Technology (PolSL)
Aurelia Rybak,,
-
, Waldemar Kaszuwara (FMSE / DCFM)
Waldemar Kaszuwara,,
- Division of Construction and Functional Materials
, Mariusz Nyc (FM)
Mariusz Nyc,,
- Faculty of Mechatronics
, Monika Auguścik (FMSE / DSMP)
Monika Auguścik,,
- Division of Ceramic Materials and Polymers
Journal seriesSeparation and Purification Technology, ISSN 1383-5866, (N/A 140 pkt)
Issue year2019
Vol210
Pages479-490
ASJC Classification1506 Filtration and Separation; 1602 Analytical Chemistry
DOIDOI:10.1016/j.seppur.2018.08.032
Languageen angielski
Score (nominal)140
Score sourcejournalList
ScoreMinisterial score = 140.0, 30-12-2019, ArticleFromJournal
Publication indicators Scopus Citations = 1; WoS Citations = 1; Scopus SNIP (Source Normalised Impact per Paper): 2016 = 1.394; WoS Impact Factor: 2018 = 5.107 (2) - 2018=4.551 (5)
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