Thermal behaviour and safety of 1,3,7,9-tetranitrodibenzo-1,3a,4,6a-tetraazapentalen (z-TACOT)

Tomasz Gołofit

Abstract

1,3,7,9-tetranitrodibenzo-1,3a,4,6a-tetraazapentalen (z-TACOT) is a thermostable compound which exhibits low-sensitivity to external stimuli. At elevated temperature it undergoes thermal decomposition. Thermal properties and safety of z-TACOT use in terms of the heat-explosion hazard were examined. The obtained kinetic parameters of the decomposition reaction and thermal capacity of z-TACOT were used to determine the maximum safe temperature of technological processes which involve z-TACOT. The temperature is 266 °C. Based on the attained safety parameters z-TACOT can be classified as a non-reactive, stable compound which does not exhibit dangerous behaviour in the Koenen test
Author Tomasz Gołofit (FC / DH-EM)
Tomasz Gołofit,,
- Department Of High-Energetic Materials
Journal seriesThermochimica Acta, ISSN 0040-6031, (A 30 pkt)
Issue year2018
Vol667
Pages59-64
Publication size in sheets0.5
Keywords in Englishthermal decomposition kinetic parameters ADT24 explosives thermal explosion
ASJC Classification1606 Physical and Theoretical Chemistry; 3104 Condensed Matter Physics; 3105 Instrumentation
DOIDOI:10.1016/j.tca.2018.07.010
Languageen angielski
File
wdpb_publikacje_pliki_plik_publikacja_3477_org.pdf 1.08 MB
Score (nominal)30
ScoreMinisterial score = 30.0, 23-09-2019, ArticleFromJournal
Publication indicators WoS Citations = 0; Scopus SNIP (Source Normalised Impact per Paper): 2017 = 1.167; WoS Impact Factor: 2017 = 2.189 (2) - 2017=2.501 (5)
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