Activation of CO2 by tBuZnOH species: efficient routes to novel nanomaterials based on zinc carbonates

Kamil Sokołowski , Wojciech Bury , Iwona Justyniak , Anna M. Cieślak , Małgorzata Wolska , Katarzyna Sołtys , Igor Dzięcielewski , Janusz Lewiński

Abstract

We report on the activation of CO2 by the well-defined alkylzinc hydroxide (tBuZnOH)6 in the absence and presence of tBu2Zn as an external proton acceptor. The slight modifications in reaction systems involving organozinc precursors enable control of the reaction products with high selectivity leading to the isolation of the mesoporous solid based on ZnCO3 nanoparticles or an unprecedented discrete alkylzinc carbonate [(tBuZn)2(μ5-CO3)]6 cluster with the Zn–C bond intact, respectively.
Author Kamil Sokołowski - [Institute of Physical Chemistry of the Polish Academy of Sciences]
Kamil Sokołowski,,
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, Wojciech Bury (FC / DCOC)
Wojciech Bury,,
- Department Of Catalysis And Organometallic Chemistry
, Iwona Justyniak - [Institute of Physical Chemistry of the Polish Academy of Sciences]
Iwona Justyniak,,
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, Anna M. Cieślak - [Institute of Physical Chemistry of the Polish Academy of Sciences]
Anna M. Cieślak,,
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, Małgorzata Wolska (FC / DCOC)
Małgorzata Wolska,,
- Department Of Catalysis And Organometallic Chemistry
, Katarzyna Sołtys - [Institute of Physical Chemistry of the Polish Academy of Sciences]
Katarzyna Sołtys,,
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, Igor Dzięcielewski - [High Pressure Research Center of the Polish Academy of Sciences]
Igor Dzięcielewski,,
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, Janusz Lewiński (FC / DCOC)
Janusz Lewiński,,
- Department Of Catalysis And Organometallic Chemistry
Journal seriesChemical Communications, ISSN 1359-7345
Issue year2013
Vol49
No46
Pages5271-5273
Publication size in sheets0.3
ASJC Classification2505 Materials Chemistry; 2506 Metals and Alloys; 2508 Surfaces, Coatings and Films; 1600 General Chemistry; 2503 Ceramics and Composites; 2504 Electronic, Optical and Magnetic Materials; 1503 Catalysis
DOIDOI:10.1039/C3CC41639A
URL http://pubs.rsc.org/en/content/articlepdf/2013/cc/c3cc41639a
Languageen angielski
File
chemcomm2013_co2.pdf 1.45 MB
Score (nominal)40
Score sourcejournalList
ScoreMinisterial score = 40.0, 03-02-2020, ArticleFromJournal
Ministerial score (2013-2016) = 40.0, 03-02-2020, ArticleFromJournal
Publication indicators Scopus Citations = 9; WoS Citations = 8; Scopus SNIP (Source Normalised Impact per Paper): 2013 = 1.367; WoS Impact Factor: 2013 = 6.718 (2) - 2013=6.485 (5)
Citation count*5 (2015-06-01)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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