1,4-Phenylene-bis-((1-methyl-1H-pyrazol-5-yl)borinic 8-oxyquinolinate) as a photoredox catalyst in the atom transfer radical addition of iodoperfluoroalkanes to alkenyl groups bearing organoboron compounds
Marcin Kublicki , Błażej Ogonowski , Dariusz Wieczorkowski , Krzysztof Durka , Tomasz Kliś
AbstractThe key photocatalytic properties of a transition-metal-free heteroleptic complex derived from 1,4-phenyldiboronic acid were evaluated. This compound was utilized in the atom transfer radical addition of iodoperfluoroalkanes to a series of alkenyl group bearing organoboron compounds. The products of these reactions retained the BC bond, and Suzuki-Miyaura coupling of one product gave biphenyl derivatives. The X-ray analysis of one of the obtained perfluoroalkylated boronic acids revealed the presence of open star-shaped channels.
|Journal series||Tetrahedron Letters, ISSN 0040-4039, (A 25 pkt)|
|Publication size in sheets||0.5|
|Keywords in English||Photoredox catalysisPerfluoroalkanesOrganoboranesQuinoline|
|Score||= 25.0, 17-07-2019, ArticleFromJournal|
|Publication indicators||: 2016 = 0.635; : 2017 = 2.125 (2) - 2017=1.954 (5)|
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