Isomeric and Isostructural Oligothienylsilanes–Structurally Similar, Physicochemically Different: The Effect of Interplay between C–H···C(π), S···C(π), and Chalcogen S···S Interactions

Krzysztof Durka , Krzysztof Gontarczyk , Sergiusz Luliński , Janusz Serwatowski , Krzysztof Woźniak

Abstract

We present detailed investigations of the structure−energy−property relationships for a series of oligothienylsilanes using a combination of experimental and computational procedures. Despite the fact that all studied systems show a very high level of structural similarity, they revealed distinct physicochemical behavior. This is due to a different distribution of C−H···C(π), S···C(π), and S···S interactions within the corresponding crystal structures.
Author Krzysztof Durka ZChF
Krzysztof Durka,,
- Department Of Physical Chemistry
, Krzysztof Gontarczyk ZChF
Krzysztof Gontarczyk,,
- Department Of Physical Chemistry
, Sergiusz Luliński ZChF
Sergiusz Luliński,,
- Department Of Physical Chemistry
, Janusz Serwatowski ZChF
Janusz Serwatowski,,
- Department Of Physical Chemistry
, Krzysztof Woźniak
Krzysztof Woźniak,,
-
Journal seriesCrystal Growth and Design, ISSN 1528-7483
Issue year2016
Vol16
No8
Pages4292-4308
Publication size in sheets0.8
DOIDOI:10.1021/acs.cgd.6b00358
URL http://pubs.acs.org/doi/full/10.1021/acs.cgd.6b00358
Languageen angielski
File
acs%2Ecgd%2E6b00358.pdf (file archived - login or check accessibility on faculty) acs%2Ecgd%2E6b00358.pdf 5.51 MB
Score (nominal)40
ScoreMinisterial score = 35.0, 28-11-2017, ArticleFromJournal
Ministerial score (2013-2016) = 40.0, 28-11-2017, ArticleFromJournal
Publication indicators WoS Impact Factor: 2016 = 4.055 (2) - 2016=4.054 (5)
Citation count*0
Cite
Share Share



* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
Back