Mixed-ligand terbium terephthalates: Synthesis, photophysical and thermal properties and use for luminescent terbium terephthalate thin film deposition

Valentina V. Utochnikova , Oksana Pietraszkiewicz , Małgorzata Kozbiał , Paweł Gierycz , Marek Pietraszkiewicz , Natalia P. Kuzmina

Abstract

Addition of potassium terephthalate K2tph to an aqueous solution of a mixture of terbium nitrate and ancillary ligands L resulted in the formation of mixed-ligand terbium terephthalates Tb2tph3(TPPO)8(H2O)4 (II), Tb2tph3(TOPO)2(H2O)4 (III), Tb2tph3(diglyme)2(H2O) (IV), Tb2tph3(tetraglyme)4(H2O)3 (V), Tb2tph3(Phen)2(H2O)2 (VI). The composition of the mixed-ligand complexes (MLCs) was confirmed by elemental analysis, Raman spectroscopy, thermal analysis, and luminescent spectroscopy. According to the thermal analysis data, II–V exhibit lower thermal stability in comparison with the terephthalate hydrate Tb2tph3(H2O)4 (I). MLCs II, IV, and V are able to eliminate ancillary ligands, followed by formation of anhydrous Tb2tph3, while in case of III and IV ligand elimination is accompanied by partial thermal decomposition of Tb2tph3. Solubility tests showed that MLC II exhibits sufficient solubility in acetonitrile for thin film deposition. Thus thin films of II were deposited by spin-coating, and luminescent thin films of Tb2tph3 were obtained for the first time by thermal treatment of II films.
Author Valentina V. Utochnikova
Valentina V. Utochnikova,,
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, Oksana Pietraszkiewicz
Oksana Pietraszkiewicz,,
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, Małgorzata Kozbiał
Małgorzata Kozbiał,,
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, Paweł Gierycz (FCPE / DSP) - [Institute of Physical Chemistry Polish Academy of Sciences (IChF PAN) [Polish Academy of Sciences (PAN)]]
Paweł Gierycz,,
- Department of Separation Processes
- Instytut Chemii Fizycznej Polskiej Akademii Nauk
, Marek Pietraszkiewicz
Marek Pietraszkiewicz,,
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, Natalia P. Kuzmina
Natalia P. Kuzmina,,
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Journal seriesJournal of Photochemistry and Photobiology A-Chemistry, ISSN 1010-6030
Issue year2013
Vol253
Pages72-80
Publication size in sheets0.5
Keywords in Englishterbium terephtalate, mixed-ligand complexes, luminescent thin films
ASJC Classification3100 General Physics and Astronomy; 1500 General Chemical Engineering; 1600 General Chemistry
DOIDOI:10.1016/j.jphotochem.2012.12.021
URL http://ac.els-cdn.com/S1010603012005904/1-s2.0-S1010603012005904-main.pdf?_tid=5672db74-e9fb-11e6-97f2-00000aacb361&acdnat=1486117817_28735cf0d6d52a9305cd53975193c4eb
Languageen angielski
File
Utochnikova V.V. - Mixed-ligand terbium terephthalate....pdf 931.36 KB
Score (nominal)25
Score sourcejournalList
ScoreMinisterial score = 25.0, 22-04-2020, ArticleFromJournal
Ministerial score (2013-2016) = 25.0, 22-04-2020, ArticleFromJournal
Publication indicators WoS Citations = 20; GS Citations = 3.0; Scopus SNIP (Source Normalised Impact per Paper): 2013 = 1.013; WoS Impact Factor: 2013 = 2.291 (2) - 2013=2.475 (5)
Citation count*3 (2015-02-07)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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