A ferrocene-templated Pd-bearing molecular reactor

Artur Kasprzak , Piotr Guńka

Abstract

High-yield, chromatography-free syntheses of a ferrocene-templated molecular cage and its Pd-bearing derivative are presented. The formation of a symmetric cage-type structure was confirmed by single-crystal X-ray diffraction analysis. The Pd-bearing cage was used as an innovative catalyst for the efficient synthesis of 1,1'-biphenyls under mild conditions. The presented catalyst is reusable and 1,1'-biphenyls can be obtained efficiently in a gram scale process.

Author Artur Kasprzak (FC / DOC)
Artur Kasprzak,,
- Department Of Organic Chemistry
, Piotr Guńka (FC / CofIC)
Piotr Guńka,,
- Chair Of Inorganic Chemistry
Journal seriesDalton Transactions, ISSN 1477-9226, e-ISSN 1477-9234
Issue year2020
Vol49
Pages6974-6979
ASJC Classification1604 Inorganic Chemistry
DOIDOI:10.1039/d0dt01366h
Languageen angielski
Score (nominal)140
Score sourcejournalList
ScoreMinisterial score = 140.0, 15-07-2020, ArticleFromJournal
Publication indicators Scopus Citations = 0; Scopus SNIP (Source Normalised Impact per Paper): 2018 = 0.9; WoS Impact Factor: 2018 = 4.052 (2) - 2018=3.813 (5)
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