New ionic liquid [P4,4,4,4][NTf2] in bio-butanol extraction on investigation of limiting activity coefficients

Urszula Domańska-Żelazna , Michał Wlazło , Monika Karpińska , Maciej Zawadzki

Abstract

The limiting activity coefficients () for 65 solutes and water in the tetrabutylphosphonium bis{(trifluomethyl)sulfonyl}imide ionic liquid (IL), [P4,4,4,4][NTf2] were determined by gas-liquid chromatography at six temperatures in range of (358.15–408.15) K. The DSC data are presented for new, synthesized by us [P4,4,4,4][NTf2]. The thermodynamic functions, the limiting partial molar excess Gibbs energy, enthalpy and entropy were calculated. The values of selectivity and capacity for water/butan-1-ol separation problem were calculated from and compared to literature values for phosphonium-based or other selected ionic liquids for the same separation problem. On the bases of the results the intermolecular interactions of the chosen IL and solutes was discussed. The data presented here shows that [P4,4,4,4][NTf2] reveals second large ever published selectivity for the water/butan-1-ol separation.
Author Urszula Domańska-Żelazna (FC / DPC) - [Instytut Chemii Przemysłowej im. prof. Ignacego Mościckiego, Thermodynamic Research Unit, School of Chemical Engineering]
Urszula Domańska-Żelazna,,
- Department Of Physical Chemistry
- Instytut Chemii Przemysłowej im. prof. Ignacego Mościckiego
- Thermodynamic Research Unit, School of Chemical Engineering
, Michał Wlazło (FC / DPC)
Michał Wlazło,,
- Department Of Physical Chemistry
, Monika Karpińska (FC / DPC)
Monika Karpińska,,
- Department Of Physical Chemistry
, Maciej Zawadzki (FC / DPC)
Maciej Zawadzki,,
- Department Of Physical Chemistry
Journal seriesFluid Phase Equilibria, ISSN 0378-3812, (A 30 pkt)
Issue year2018
Vol475
Pages89-94
Publication size in sheets0.5
Keywords in EnglishIonic liquid [P4,4,4,4][NTf2]Experimental limiting activity coefficientsThermodynamicsSeparation
ASJC Classification1606 Physical and Theoretical Chemistry; 3100 General Physics and Astronomy; 1500 General Chemical Engineering
DOIDOI:10.1016/j.fluid.2018.07.028
URL https://www.sciencedirect.com/science/article/pii/S0378381218302991
Languageen angielski
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1-s2.0-S0378381218302991-main.pdf 809.24 KB
Score (nominal)30
ScoreMinisterial score = 30.0, 23-09-2019, ArticleFromJournal
Publication indicators Scopus SNIP (Source Normalised Impact per Paper): 2017 = 1.033; WoS Impact Factor: 2017 = 2.197 (2) - 2017=2.214 (5); Scopus Citations = 3
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