Spectroscopic properties and martensitic phase transition of Y4Al2O9:Ce single crystals under high pressure

Yongjie Wang , R. Hrubiak , Sebastian Turczyński , D.A. Pawlak , Michał Malinowski , Damian Włodarczyk , K. Kosyl , W. Paszkowicz , H. Przybylinska , A. Wittlin , A. Kamińska , Ya Zhydachevskyy , M.G. Brik , Lily Li , Chong-Geng Ma , Andrzej Suchocki


High pressure studies of monoclinic yttrium aluminum oxide single crystals (Y4Al2O9-YAM) doped with Ce3+ ions grown by micro-pulling-down method are report ed. The results of absorption measurements in the mid-infrared prove the existence of four different sites in which Ce3+ ions substitute Y ions, in accordance with the crystallo graphic structure of YAM. The lowest 5d level of Ce3+ is located very close to the bottom of the conduction band for two of four Ce3+ related centers at ambient pressure, which results in strong temperature quenching of their luminescence. Two other Ce3+ centers do not emit at ambient pressure since their 5d levels are resonant with the conduction band. Application of high pressure above 11 GPa restores their luminescence. Consequences of such energy structure of various Ce3+ sites in YAM for the Dorenbos theory are discussed. The bandgap energy of YAM is found to be 5.93 eV, which is the smallest out of the three yttrium aluminum oxides. High-pressure synchrotron angle dispersive x-ray di ffraction and Raman scattering measurements identify a phase transition occurring at pressures between 8 and 11 GPa, which has martensitic character. The second phase transition to another structure (likely with hexagonal symmetry) occurs at a pressure around 16 GPa.
Author Yongjie Wang
Yongjie Wang,,
, R. Hrubiak
R. Hrubiak,,
, Sebastian Turczyński
Sebastian Turczyński,,
, D.A. Pawlak
D.A. Pawlak,,
, Michał Malinowski (FEIT / MO)
Michał Malinowski,,
- The Institute of Microelectronics and Optoelectronics
, Damian Włodarczyk
Damian Włodarczyk,,
, K. Kosyl
K. Kosyl,,
, W. Paszkowicz
W. Paszkowicz,,
, H. Przybylinska
H. Przybylinska,,
, A. Wittlin
A. Wittlin,,
et al.`
Journal seriesActa Materialia, ISSN 1359-6454, (A 45 pkt)
Issue year2019
No15 February 2019
Publication size in sheets0.5
Keywords in EnglishSingle crystal; Luminescence; High pressure; X-ray diffraction; Phase transition
ASJC Classification2504 Electronic, Optical and Magnetic Materials
URL https://www.sciencedirect.com/science/article/pii/S1359645418309340?via%3Dihub
Languageen angielski
Score (nominal)45
ScoreMinisterial score = 45.0, 08-01-2019, ArticleFromJournal
Ministerial score (2013-2016) = 45.0, 08-01-2019, ArticleFromJournal
Publication indicators Scopus SNIP (Source Normalised Impact per Paper): 2017 = 2.737; WoS Impact Factor: 2017 = 6.036 (2) - 2017=6.174 (5)
Citation count*
Share Share

Get link to the record

* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.