Activity coefficients at infinite dilution of organic solvents and water in 1-butyl-3-methylimidazolium dicyanamide. A literature review of hexane/hex-1-ene separation

Urszula Domańska-Żelazna , Michał Wlazło , Monika Karpińska


The work presented focused on the experimental data of the activity coefficients at infinite dilution, (View the MathML source) of several solutes in ionic liquid of 1-butyl-3-methylimidazolium dicyanamide, [BMIM][DCA]. The values of View the MathML source for 64 solutes, including alkanes, cycloalkanes, alkenes, alkynes, aromatic hydrocarbons, alcohols, water, ethers, ketones, acetonitrile, pyridine, 1-nitropropane, thiophene, and esters in [BMIM][DCA] were determined by gas–liquid chromatography at six temperatures in range of (318.15–368.15) K. The gas–liquid partition coefficients were calculated for all solutes. The partial molar excess Gibbs energy, enthalpy and entropy at infinite dilution were calculated from the experimental View the MathML source values. The [BMIM][DCA] was discussed as a solvent for the different types of separation problems with special attention to the separation of hexane/hex-1-ene, cyclohexane/cyclohexene and ethylbenzene/styrene. This work discuss a particular type of mixture made up of small hydrocarbons (alkanes) and their unsaturated counterparts (alkenes). The separating ability of the investigated ionic liquid was compared with the previously investigated 1-butyl-3-methylimidazolium-based, and dicyanoamide-based ILs for three chosen separation problems. Additionally, a literature review of View the MathML source for the hexane/hex-1-ene separation problem at T = 323.15 K is presented for the years 2010–2015. It was found that several ILs may replace conventional solvents. The proposed [BMIM][DCA] may be used as an alternative solvent for the separation of alkenes from alkanes.
Author Urszula Domańska-Żelazna (FC / DPC)
Urszula Domańska-Żelazna,,
- Department Of Physical Chemistry
, Michał Wlazło (FC / DPC)
Michał Wlazło,,
- Department Of Physical Chemistry
, Monika Karpińska (FC / DPC)
Monika Karpińska,,
- Department Of Physical Chemistry
Journal seriesFluid Phase Equilibria, ISSN 0378-3812
Issue year2016
Publication size in sheets0.55
Keywords in EnglishExperimental activity coefficients at infinite dilution; Ionic liquid [BMIM][DCA]; Literature review hexane/hex-1-ene; Thermodynamics; Separation
ASJC Classification1606 Physical and Theoretical Chemistry; 3100 General Physics and Astronomy; 1500 General Chemical Engineering
Languageen angielski
1-s2.0-S0378381216300541-main.pdf 740.47 KB
Score (nominal)30
Score sourcejournalList
ScoreMinisterial score = 30.0, 01-02-2020, ArticleFromJournal
Ministerial score (2013-2016) = 30.0, 01-02-2020, ArticleFromJournal
Publication indicators Scopus Citations = 39; Scopus SNIP (Source Normalised Impact per Paper): 2016 = 1.187; WoS Impact Factor: 2016 = 2.473 (2) - 2016=2.499 (5)
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