Polymers for electronics and spintronics

Piotr Bujak , Irena Kulszewicz-Bajer , Małgorzata Zagórska , Vincent Maurel , Ireneusz Wielgus , Adam Proń

Abstract

This critical review is devoted to semiconducting and high spin polymers which are of great scientific interest in view of further development of the organic electronics and the emerging organic spintronic fields. Diversified synthetic strategies are discussed in detail leading to high molecular mass compounds showing appropriate redox (ionization potential (IP), electron affinity (EA)), electronic (charge carrier mobility, conductivity), optoelectronic (electroluminescence, photoconductivity) and magnetic (magnetization, ferromagnetic spin interactions) properties and used as active components of devices such as n- and p-channel field effect transistors, ambipolar light emitting transistors, light emitting diodes, photovoltaic cells, photodiodes, magnetic photoswitches, etc. Solution processing procedures developed with the goal of depositing highly ordered and oriented films of these polymers are also described. This is completed by the description of principal methods that are used for characterizing these macromolecular compounds both in solution and in the solid state. These involve various spectroscopic methods (UV-vis-NIR, UPS, pulse EPR), electrochemistry and spectroelectrochemistry, magnetic measurements (SQUID), and structural and morphological investigations (X-ray diffraction, STM, AFM). Finally, four classes of polymers are discussed in detail with special emphasis on the results obtained in the past three years: (i) high IP, (ii) high |EA|, (iii) low band gap and (iv) high spin ones.
Author Piotr Bujak (FC / CPCT)
Piotr Bujak,,
- Chair Of Polymer Chemistry And Technology
, Irena Kulszewicz-Bajer (FC / CPCT)
Irena Kulszewicz-Bajer,,
- Chair Of Polymer Chemistry And Technology
, Małgorzata Zagórska (FC / CPCT)
Małgorzata Zagórska,,
- Chair Of Polymer Chemistry And Technology
, Vincent Maurel - [CEA Grenoble]
Vincent Maurel,,
-
-
, Ireneusz Wielgus (FC / CPCT)
Ireneusz Wielgus,,
- Chair Of Polymer Chemistry And Technology
, Adam Proń (FC / CPCT)
Adam Proń,,
- Chair Of Polymer Chemistry And Technology
Journal seriesChemical Society Reviews, ISSN 0306-0012
Issue year2013
Vol42
No23
Pages8895-8999
Publication size in sheets5.2
ASJC Classification1600 General Chemistry
DOIDOI:10.1039/C3CS60257E
URL http://pubs.rsc.org/en/Content/ArticleLanding/2013/CS/c3cs60257e#!divAbstract
Languageen angielski
File
c3cs60257e.pdf 9.28 MB
Score (nominal)50
Score sourcejournalList
ScoreMinisterial score = 50.0, 25-07-2020, ArticleFromJournal
Ministerial score (2013-2016) = 50.0, 25-07-2020, ArticleFromJournal
Publication indicators WoS Citations = 216; Scopus Citations = 222; GS Citations = 279.0; Scopus SNIP (Source Normalised Impact per Paper): 2013 = 6.492; WoS Impact Factor: 2013 = 30.425 (2) - 2013=33.159 (5)
Citation count*289 (2020-09-15)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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