Thermal degradation of organic additives used in colloidal shaping of ceramics investigated by the coupled DTA/TG/MS analysis

Paulina Wiecińska

Abstract

The paper presents the analysis of thermal decomposition of selected organic additives, which are commonly used in shaping of ceramic materials by colloidal methods. Shaping of ceramics requires using different additives which then are burned out during sintering process. For this reason the knowledge about thermal degradation of organics used, as well as decomposition products, seems to be very important from the application point of view. The analyzed substances were as follows: diammonium hydrocitrate, citric acid, ammonium salt of acrylic polymer, L-ascorbic acid, N,N,N’,N’-tetramethylethylenediamine and ammonium persulfate. The thermal analysis has been done on the apparatus coupled with mass spectrometer what allowed to observe what types of gasses are released to the atmosphere during heating. The obtained results showed important differences in thermal degradation of organic additives. It was possible to determine at what temperature regions harmful gases like N2O, NO2 or SO2 are released from the organics and which additives can be treated as environmentally friendly.
Author Paulina Wiecińska KTCh
Paulina Wiecińska,,
- Chair of Chemical Technology
Journal seriesJournal of Thermal Analysis and Calorimetry, ISSN 1388-6150
Issue year2016
Vol123
No2
Pages1419-1430
Publication size in sheets0.55
Keywords in Englishthermal degradation, organics, colloidal shaping, mass spectrometer
DOIDOI:10.1007/s10973-015-5075-1
URL http://link.springer.com/article/10.1007%2Fs10973-015-5075-1
project-. Project leader: Wiecińska Paulina, , Phone: 22 234 7413, start date 21-07-2015, planned end date 18-10-2018, 2014/15/D/ST5/02574, Implemented
WCh Projects financed by NSC [Projekty finansowane przez NCN]
Languageen angielski
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art%3A10.1007%2Fs10973-015-5075-1.pdf (file archived - login or check accessibility on faculty) art%3A10.1007%2Fs10973-015-5075-1.pdf 3.13 MB
Score (nominal)25
ScoreMinisterial score = 20.0, 28-11-2017, ArticleFromJournal
Ministerial score (2013-2016) = 25.0, 28-11-2017, ArticleFromJournal
Publication indicators WoS Impact Factor: 2016 = 1.953 (2) - 2016=1.69 (5)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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