Purification of Hexabenzylhexaazaisowurtzitane

Tomasz Gołofit , Paweł Maksimowski

Abstract

Hexabenzylhexaazaisowurtzitane (HBIW) is produced by a condensation reaction of benzylamine with glyoxal in suitable organic solvents in the presence of protonic acid catalysts. Impurities have to be removed prior to the subsequent stages of the synthesis of CL-20. The effectiveness of HBIW purification by recrystallization from a variety of solvents has been studied here. This method was compared with a novel approach suggested for HBIW purification that consists of prolonged heating of the crude product in boiling methanol. This new purification method allows the product to be prepared in satisfactory purity, it is simple and easily performed on a large-scale.
Author Tomasz Gołofit ZMW
Tomasz Gołofit,,
- Department Of High-Energetic Materials
, Paweł Maksimowski ZMW
Paweł Maksimowski,,
- Department Of High-Energetic Materials
Journal seriesCentral European Journal of Energetic Materials, ISSN 1733-7178
Issue year2016
Vol13
No4
Pages1038-1050
Publication size in sheets0.6
Keywords in EnglishHBIW, CL-20, purification, differential scanning calorimetry, cryometric method
DOIDOI:10.22211/cejem/67428
URL http://www.wydawnictwa.ipo.waw.pl/cejem/Vol-13-Number-4-2016/Golofit.pdf
Languageen angielski
File
Golofit.pdf (file archived - login or check accessibility on faculty) Golofit.pdf 483.06 KB
Score (nominal)30
ScoreMinisterial score = 25.0, 28-11-2017, ArticleFromJournal
Ministerial score (2013-2016) = 30.0, 28-11-2017, ArticleFromJournal
Publication indicators WoS Impact Factor: 2016 = 1.041 (2) - 2016=1.403 (5)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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