Self-Organized, One-Dimensional Periodic Structures in a Gold Nanoparticle-Doped Nematic Liquid Crystal Composite

Piotr Lesiak , Karolina Bednarska , Wiktor Lewandowski , Michał Wójcik , S. Polakiewicz , M. Bagiński , Tomasz Osuch , Konrad Markowski , Kamil Orzechowski , Michał Makowski , Jan Bolek , Tomasz Woliński

Abstract

Composite structures exhibiting a periodic arrangement of building blocks can be found in natural systems at different length scales. Recreating such systems in artificial composites using the principles of self-assembly has been a great challenge, especially for 1D microscale systems. Here, we present a purposely designed composite material consisting of gold nanoparticles and a nematic liquid crystal matrix that has the ability to self-create a periodic structure in the form of a one-dimensional photonic lattice through a phase separation process occurring in a confined space. Our strategy is based on the use of a thermoswitchable medium that reversibly and quickly responds to both heating and cooling. We find that the period of the structure is strongly related to the size of the confining space. We believe that our findings will allow us to not only better understand the phase separation process in multicomponent soft/colloid mixtures with useful optical properties but also improve our understanding of the precise assembly of advanced materials into one-dimensional periodic systems, with prospective applications in future photonic technologies.
Author Piotr Lesiak (FP / OPD)
Piotr Lesiak,,
- Optics and Photonics Division
, Karolina Bednarska (FP / OPD)
Karolina Bednarska,,
- Optics and Photonics Division
, Wiktor Lewandowski - [University of Warsaw (UW), MNiSW [80]]
Wiktor Lewandowski,,
-
- Uniwersytet Warszawski
, Michał Wójcik - [University of Warsaw (UW), MNiSW [80]]
Michał Wójcik,,
-
- Uniwersytet Warszawski
, S. Polakiewicz - [University of Warsaw (UW), MNiSW [80]]
S. Polakiewicz,,
-
- Uniwersytet Warszawski
, M. Bagiński - [University of Warsaw (UW), MNiSW [80]]
M. Bagiński,,
-
- Uniwersytet Warszawski
, Tomasz Osuch (FEIT / PE)
Tomasz Osuch,,
- The Institute of Electronic Systems
, Konrad Markowski (FEIT / PE)
Konrad Markowski,,
- The Institute of Electronic Systems
, Kamil Orzechowski (FP / OPD)
Kamil Orzechowski,,
- Optics and Photonics Division
, Michał Makowski (FP / OPD)
Michał Makowski,,
- Optics and Photonics Division
et al.`
Journal seriesACS Nano, [ACS NANO], ISSN 1936-0851, e-ISSN 1936-086X, (N/A 200 pkt)
Issue year2019
Vol13
No9
Pages10154-10160
Publication size in sheets0.5
Keywords in Englishnematic liquid crystal; nanoparticles; self-assembly; self-organization; phase separation; liquid crystal composite; periodic structure
ASJC Classification2200 General Engineering; 2500 General Materials Science; 3100 General Physics and Astronomy
DOIDOI:10.1021/acsnano.9b03302
URL https://www2.scopus.com/inward/record.uri?eid=2-s2.0-85072561237&doi=10.1021%2facsnano.9b03302&partnerID=40&md5=e7b4ac404dedc6a704f49f2b44b0d2f9
Languageen angielski
Score (nominal)200
Score sourcejournalList
ScoreMinisterial score = 200.0, 08-01-2020, ArticleFromJournal
Publication indicators WoS Citations = 0; Scopus Citations = 1; Scopus SNIP (Source Normalised Impact per Paper): 2018 = 2.447; WoS Impact Factor: 2018 = 13.903 (2) - 2018=15.149 (5)
Citation count*1 (2020-01-26)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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