Sulfur tolerant Co–Mo–K catalysts supported on carbon materials for sour gas shift process — effect of support modification
Katarzyna Antoniak-Jurak , Paweł Kowalik , Marcin Konkol , Wiesław Próchniak , Robert Bicki , Wioletta Raróg-Pilecka , Piotr Kuśtrowski , Janusz Ryczkowski
AbstractThe effect of steam gasification on the surface composition, surface area, pore size distribution as well as on the morphology of the carbon supports has been investigated. Materials have been characterized by nitrogen physisorption, mercury porosimetry, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). Model samples of the Co–Mo–K catalysts with the same composition have been prepared on carbon supports differing in the temperature of steam gasification process. Catalytic activity measurements have been carried out in a gradientless reactor in a kinetic regime at low partial pressures of reagents. A relationship between textural parameters of the supports and the catalysts activity has been estimated. The highest activity in the SGS process has been determined for the Co–Mo–K/SRO/40.49 supported catalyst.
|Journal series||Fuel Processing Technology, ISSN 0378-3820|
|Publication size in sheets||0.5|
|Keywords in English||Sour gas shift, Carbon supported Co–Mo–K catalysts, Carbon black composites, Mesoporous carbon support|
|Score|| = 35.0, 28-11-2017, ArticleFromJournal|
= 40.0, 28-11-2017, ArticleFromJournal
|Publication indicators||: 2016 = 3.752 (2) - 2016=4.051 (5)|
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