Excess Enthalpies in Binary Systems of Isomeric C8 Aliphatic Monoethers with Acetonitrile and Their Description by the COSMO-SAC Model

Łukasz Ruszczyński , Mateusz Reda , Marek Królikowski , Marek Gliński , Tadeusz Hofman


The excess enthalpies at 298.15 and 308.15 K for six binary mixtures of acetonitrile + C8 aliphatic ether {heptyl methyl ether CH3OnC7H15, or ethylhexyl ether C2H5OnC6H13, or pentyl propyl ether nC3H7OnC5H11, or isopentyl propyl ether nC3H7Oi C5H11, or dibutyl ether nC4H9OnC4H9, or butyl isobutyl ether nC4H9OiC4H9} have been determined by isothermal titration calorimetry using the TA Instruments (model TAM III) calorimeter. The possibility of the COSMO-SAC model to account for the thermodynamic differences between these systems has been tested.
Author Łukasz Ruszczyński (FC / DPC)
Łukasz Ruszczyński,,
- Department Of Physical Chemistry
, Mateusz Reda (FC / DPC)
Mateusz Reda,,
- Department Of Physical Chemistry
, Marek Królikowski (FC / DPC)
Marek Królikowski,,
- Department Of Physical Chemistry
, Marek Gliński (FC / CChT)
Marek Gliński,,
- Chair of Chemical Technology
, Tadeusz Hofman (FC / DPC)
Tadeusz Hofman,,
- Department Of Physical Chemistry
Journal seriesJournal of Chemical and Engineering Data, ISSN 0021-9568
Issue year2016
Publication size in sheets0.5
ASJC Classification1500 General Chemical Engineering; 1600 General Chemistry
URL http://pubs.acs.org/doi/abs/10.1021/acs.jced.5b00838
Languageen angielski
acs%2Ejced%2E5b00838_3.pdf 671.6 KB
Score (nominal)30
Score sourcejournalList
ScoreMinisterial score = 30.0, 17-08-2020, ArticleFromJournal
Ministerial score (2013-2016) = 30.0, 17-08-2020, ArticleFromJournal
Publication indicators Scopus Citations = 0; WoS Citations = 0; Scopus SNIP (Source Normalised Impact per Paper): 2016 = 1.104; WoS Impact Factor: 2016 = 2.323 (2) - 2016=2.448 (5)
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