Pervaporation applied for dewatering of reaction mixture during esterification

Andrzej Ryszard Krasiński , Patrycja Wierzba , Agata Grudzień , Halina Hajmowicz , Krzysztof Zawada , Ludwik Synoradzki

Abstract

In this work the esterification of diethyl tartrate was studied. The research was focused on the enhancement of reversible reaction yield, which is accomplished by dewatering of the reaction mixture. The removal of water shifts the equilibrium towards the main product. Pervaporation was applied for this purpose, and results were compared to distillation. The advantages and limitations of both processes are discussed. The experimental part consists of dewatering of mixture after the reaction had reached the equilibrium, and was subsequently fed to the test rig equipped with a single zeolite membrane purchased from Pervatech B.V. Results show a significant conversion increase as a result of water removal by pervaporation. Compared to distillation no addition of organics is necessary to efficiently remove water above the azeotrope. Nevertheless, some limitations and issues which call for optimisation are pointed out. A simple numerical model is proposed to support design and sizing of the pervaporation system. Various modes of integrated system operation are also briefly discussed.
Author Andrzej Ryszard Krasiński (FCPE / CIPE)
Andrzej Ryszard Krasiński,,
- Chair of Integrated Process Engineering
, Patrycja Wierzba (FCPE)
Patrycja Wierzba,,
- Faculty of Chemical and Process Engineering
, Agata Grudzień (FCPE)
Agata Grudzień,,
- Faculty of Chemical and Process Engineering
, Halina Hajmowicz (FC / LTP)
Halina Hajmowicz,,
- Laboratory Of Technological Processes
, Krzysztof Zawada (FC / LTP)
Krzysztof Zawada,,
- Laboratory Of Technological Processes
, Ludwik Synoradzki (FC / LTP)
Ludwik Synoradzki,,
- Laboratory Of Technological Processes
Journal seriesChemical and Process Engineering , [Inżynieria Chemiczna i Procesowa], ISSN 0208-6425, (A 15 pkt)
Issue year2016
Vol37
No1
Pages121-131
Publication size in sheets0.5
Keywords in Englishdiethyl tartrate, esterification, pervaporation, distillation, integrated process
ASJC Classification1500 General Chemical Engineering; 1600 General Chemistry
DOIDOI:10.1515/cpe-2016-0012
URL http://www.degruyter.com/view/j/cpe.2016.37.issue-1/cpe-2016-0012/cpe-2016-0012.xml
Languageen angielski
File
PERVAPORATION APPLIED FOR DEWATERING OF REACTION.pdf 4.72 MB
Score (nominal)15
Score sourcejournalList
ScoreMinisterial score = 15.0, 30-01-2020, ArticleFromJournal
Ministerial score (2013-2016) = 15.0, 30-01-2020, ArticleFromJournal
Publication indicators WoS Citations = 2; Scopus Citations = 2; Scopus SNIP (Source Normalised Impact per Paper): 2016 = 0.855; WoS Impact Factor: 2016 = 0.971 (2) - 2016=0.925 (5)
Citation count*2 (2020-02-25)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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