Microwave Plasma Chemical Vapor Deposition of SbxOy/C negative electrodes and their compatibility with lithium and sodium Hückel salts - Based, tailored electrolytes

Anna Bitner-Michalska , K. Michalczewski , Joanna Zdunek , Andrzej Ostrowski , Grażyna Żukowska , Tomasz Trzeciak , Elżbieta Żero , Jarosław Syzdek , Marek Marcinek


A synthesis of new types of SbxOy/C composite negative electrodes for lithium and sodium-ion batteries is reported. Thin layers of graphitic carbon decorated in 3D with Sb nanoparticles were produced from organic precursors triphenylantimony (III) using a one-step microwave plasma chemical vapor deposition (MPCVD) method. Thin-film SbxOy/C electrodes were electrochemically tested in lithium and sodium half cells with Li and NaTDI (2-trifluoromethyl-4,5-dicyanoimidazole lithium and sodium salts) 0.75 M electrolytes and delivered capacity of 425 mAh g-1 at C/10 discharge rate..
Author Anna Bitner-Michalska (FC)
Anna Bitner-Michalska,,
- Faculty of Chemistry
, K. Michalczewski (FC)
K. Michalczewski,,
- Faculty of Chemistry
, Joanna Zdunek (FMSE / DMD)
Joanna Zdunek,,
- Division of Materials Design
, Andrzej Ostrowski (FC / CICSST)
Andrzej Ostrowski,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Grażyna Żukowska (FC / CICSST)
Grażyna Żukowska,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Tomasz Trzeciak (FC / CICSST)
Tomasz Trzeciak,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Elżbieta Żero (FC / CICSST)
Elżbieta Żero,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Jarosław Syzdek - [Voltaiq Incorporated]
Jarosław Syzdek,,
, Marek Marcinek (FC / CICSST)
Marek Marcinek,,
- Chair Of Inorganic Chemistry And Solid State Technology
Journal seriesElectrochimica Acta, ISSN 0013-4686
Issue year2016
Publication size in sheets0.5
Keywords in Englishanode; Antimony; Lithium batteries; microwave; plasma; Sodium
ASJC Classification1603 Electrochemistry; 1500 General Chemical Engineering
URL http://www.sciencedirect.com/science/article/pii/S0013468616310271
Languageen angielski
1-s2.0-S0013468616310271-main.pdf 1.3 MB
Score (nominal)40
Score sourcejournalList
ScoreMinisterial score = 40.0, 10-06-2020, ArticleFromJournal
Ministerial score (2013-2016) = 40.0, 10-06-2020, ArticleFromJournal
Publication indicators WoS Citations = 11; Scopus Citations = 14; Scopus SNIP (Source Normalised Impact per Paper): 2016 = 1.185; WoS Impact Factor: 2016 = 4.798 (2) - 2016=4.63 (5)
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