Microwave Plasma Chemical Vapor Deposition of SbxOy/C negative electrodes and their compatibility with lithium and sodium Hückel salts - Based, tailored electrolytes

Anna Bitner-Michalska , K. Michalczewski , Joanna Zdunek , Andrzej Ostrowski , Grażyna Żukowska , Tomasz Trzeciak , Elżbieta Żero , Jarosław Syzdek , Marek Marcinek

Abstract

A synthesis of new types of SbxOy/C composite negative electrodes for lithium and sodium-ion batteries is reported. Thin layers of graphitic carbon decorated in 3D with Sb nanoparticles were produced from organic precursors triphenylantimony (III) using a one-step microwave plasma chemical vapor deposition (MPCVD) method. Thin-film SbxOy/C electrodes were electrochemically tested in lithium and sodium half cells with Li and NaTDI (2-trifluoromethyl-4,5-dicyanoimidazole lithium and sodium salts) 0.75 M electrolytes and delivered capacity of 425 mAh g-1 at C/10 discharge rate..
Author Anna Bitner-Michalska WCh
Anna Bitner-Michalska,,
- Faculty of Chemistry
, K. Michalczewski WCh
K. Michalczewski,,
- Faculty of Chemistry
, Joanna Zdunek ZPM
Joanna Zdunek,,
- Division of Materials Design
, Andrzej Ostrowski KChNTCS
Andrzej Ostrowski,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Grażyna Żukowska KChNTCS
Grażyna Żukowska,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Tomasz Trzeciak KChNTCS
Tomasz Trzeciak,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Elżbieta Żero KChNTCS
Elżbieta Żero,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Jarosław Syzdek
Jarosław Syzdek,,
-
, Marek Marcinek KChNTCS
Marek Marcinek,,
- Chair Of Inorganic Chemistry And Solid State Technology
Journal seriesElectrochimica Acta, ISSN 0013-4686
Issue year2016
Vol210
Pages395-400
Publication size in sheets0.5
Keywords in Englishanode; Antimony; Lithium batteries; microwave; plasma; Sodium
DOIDOI:10.1016/j.electacta.2016.04.175
URL http://www.sciencedirect.com/science/article/pii/S0013468616310271
Languageen angielski
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1-s2.0-S0013468616310271-main.pdf (file archived - login or check accessibility on faculty) 1-s2.0-S0013468616310271-main.pdf 1.3 MB
Score (nominal)40
ScoreMinisterial score = 40.0, 28-11-2017, ArticleFromJournal
Ministerial score (2013-2016) = 40.0, 28-11-2017, ArticleFromJournal
Publication indicators WoS Impact Factor: 2016 = 4.798 (2) - 2016=4.63 (5)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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