Transmetalation: routes to metal exchange within metal–organic frameworks

Marianne Lalonde , Wojciech Bury , Olga Karagiaridi , Z. Brown , J. T. Hupp , O. K. Farha

Abstract

The present work is a critical review of metal exchange (transmetalation) involving metal nodes and metalated struts in metal–organic frameworks. Particular emphasis is given to drawing parallels between different examples of transmetalation in order to understand the influence of coordination environment, solvents, nature of the metals and other variables on the process. We hope that the present review will be of use to those involved in the incorporation of various metal centers to create isostructural MOFs and study their properties.
Author Marianne Lalonde
Marianne Lalonde,,
-
, Wojciech Bury (FC / DCOC)
Wojciech Bury,,
- Department Of Catalysis And Organometallic Chemistry
, Olga Karagiaridi
Olga Karagiaridi,,
-
, Z. Brown
Z. Brown,,
-
, J. T. Hupp
J. T. Hupp,,
-
, O. K. Farha
O. K. Farha,,
-
Journal seriesJournal of Materials Chemistry A: materials for energy and sustainability, ISSN 2050-7488, [2050-7496]
Issue year2013
Vol1
No18
Pages5453-5468
Publication size in sheets0.75
DOIDOI:10.1039/c3ta10784a
URL http://pubs.rsc.org/en/Content/ArticleLanding/2013/TA/C3TA10784A#!divAbstract
Languageen angielski
File
jmcA2013_Met-Exch-REV.pdf 2.57 MB
Score (nominal)40
ScoreMinisterial score = 0.0, 28-11-2017, ArticleFromJournal
Ministerial score (2013-2016) = 40.0, 28-11-2017, ArticleFromJournal
Publication indicators WoS Impact Factor: 2014 = 7.443 (2) - 2014=7.449 (5)
Citation count*51 (2015-06-01)
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