Nanotubular Hydrogen-Bonded Organic Framework Architecture of 1,2-Phenylenediboronic Acid Hosting Ice Clusters

Krzysztof Durka , Katarzyna N. Jarzembska , Radosław Kamiński , Sergiusz Luliński , Janusz Serwatowski , Krzysztof Woźniak

Abstract

A nanotubular crystal network of a small-molecule compound, 1,2-phenylenediboronic acid, constituting a hydrogen-bonded organic framework (HOF) architecture is presented. In contrast to the carbon nanotubes, the intermolecular connections are based strictly on hydrogen-bonding interactions. Its uniqueness is additionally enhanced by the existence of the other two crystal phases characterized by more compact structures. Furthermore, the experiment and computational analysis show that such channels may host water clusters, such as water-based polymers similar to the ones found in the hexagonal structures of ice. Water molecules incorporated into pores interact weakly with the boronic framework and, thus, are not responsible for the framework templation.
Author Krzysztof Durka (FC / DPC)
Krzysztof Durka,,
- Department Of Physical Chemistry
, Katarzyna N. Jarzembska - [University of Warsaw (UW)]
Katarzyna N. Jarzembska,,
-
- Uniwersytet Warszawski
, Radosław Kamiński - [University of Warsaw (UW)]
Radosław Kamiński,,
-
- Uniwersytet Warszawski
, Sergiusz Luliński (FC / DPC)
Sergiusz Luliński,,
- Department Of Physical Chemistry
, Janusz Serwatowski (FC / DPC)
Janusz Serwatowski,,
- Department Of Physical Chemistry
, Krzysztof Woźniak - [University of Warsaw (UW)]
Krzysztof Woźniak,,
-
- Uniwersytet Warszawski
Journal seriesCrystal Growth and Design, ISSN 1528-7483
Issue year2013
Vol13
No10
Pages4181-4185
Publication size in sheets0.5
ASJC Classification3104 Condensed Matter Physics; 2500 General Materials Science; 1600 General Chemistry
DOIDOI:10.1021/cg401087j
URL http://pubs.acs.org/doi/abs/10.1021/cg401087j
Languageen angielski
File
7-cg401087j.pdf 3.63 MB
Score (nominal)40
Score sourcejournalList
ScoreMinisterial score = 40.0, 07-09-2020, ArticleFromJournal
Ministerial score (2013-2016) = 40.0, 07-09-2020, ArticleFromJournal
Publication indicators Scopus Citations = 26; WoS Citations = 27; GS Citations = 4.0; Scopus SNIP (Source Normalised Impact per Paper): 2013 = 1.441; WoS Impact Factor: 2013 = 4.558 (2) - 2013=4.727 (5)
Citation count*4 (2014-12-11)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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