Separation of binary mixtures hexane/hex-1-ene, cyclohexane/cyclohexene and ethylbenzene/styrene based on gamma infinity data measurements

Monika Karpińska , Michał Wlazło , Maciej Zawadzki , Urszula Domańska-Żelazna

Abstract

The activity coefficients View the MathML source at infinite dilution for 64 solutes were determined in the 1-(3-hydroxypropyl)-3-methylimidazolium dicyanamide, [N-C3OHMIM][DCA] and 58 solutes in (3-hydroxypropyl)-1-methylmorpholinium dicyanamide, [N-C3OHMMor][DCA] using the gas-liquid chromatography technique. Measurements were undertaken at six temperatures, in 10 K intervals, in the range of (298.15–368.15) K. The solutes studied included both non-polar and polar compounds, as alkanes, alkenes, and alkynes, as well as aromatic hydrocarbons, alcohols, water, ethers, ketones, acetonitrile, pyridine, 1-nitropropane, thiophene, and esters. Density, ρ, measurements for a range of temperatures (298.15–368.15) K for the synthesized, new ionic liquids (ILs) were also undertaken at pressure, p  = 101 kPa. The gas-liquid partition coefficients, KL at infinite dilution, and the fundamental thermodynamic functions, partial molar excess Gibbs energy, enthalpy and entropy at infinite dilution were calculated from the experimental data measurements. The values of selectivity and capacity for three separation cases, viz . hexane/hex-1-ene, cyclohexane/cyclohexene, and ethylbenzene/styrene were calculated from View the MathML source values and compared to literature for imidazolium-based, morfolinium-based, or dicyanamide-based, ILs. The results from the study indicate that [N-C3OHMIM][DCA] has large selectivity values for all three of the separation cases studied and that [N-C3OHMMor][DCA] has the largest selectivity ever noted for cyclohexane/cyclohexene, and ethylbenzene/styrene separation processes.
Author Monika Karpińska ZChF
Monika Karpińska,,
- Department Of Physical Chemistry
, Michał Wlazło ZChF
Michał Wlazło,,
- Department Of Physical Chemistry
, Maciej Zawadzki ZChF
Maciej Zawadzki,,
- Department Of Physical Chemistry
, Urszula Domańska-Żelazna ZChF
Urszula Domańska-Żelazna,,
- Department Of Physical Chemistry
Journal seriesJournal of Chemical Thermodynamics, ISSN 0021-9614
Issue year2018
Vol118
Pages244-254
Publication size in sheets0.5
Keywords in EnglishIonic liquids; [N-C3OHMIM[DCA] and [N-C3OHMMor][DCA]; Activity coefficients at infinite dilution; Thermodynamics; Separation
DOIDOI:10.1016/j.jct.2017.11.017
URL https://www.sciencedirect.com/science/article/pii/S0021961417304147
Languageen angielski
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2018-LLE an-en-DCA_2-JChemThermodyn.pdf (file archived - login or check accessibility on faculty) 2018-LLE an-en-DCA_2-JChemThermodyn.pdf 745.04 KB
Score (nominal)35
ScoreMinisterial score = 30.0, 21-12-2017, ArticleFromJournal
Ministerial score (2013-2016) = 35.0, 21-12-2017, ArticleFromJournal
Publication indicators WoS Impact Factor: 2016 = 2.726 (2) - 2016=2.784 (5)
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