Liquid-liquid equilibrium in binary systems of isomeric C8 aliphatic monoethers with nitromethane

Tadeusz Hofman , Mateusz Reda , Marek Gliński

Abstract

New apparatus to measure liquid–liquid or solid–liquid equilibria by a synthetic method has been built and described. It was used to determine the liquid–liquid equilibrium curves for four binary mixtures of nitromethane + {heptyl methyl ether–CH3OnC7H15, or ethyl hexyl ether–C2H5OnC6H13, or pentyl propyl ether nC3H7OnC5H11, or dibutyl ether nC4H9OnC4H9}. The influence of position of the ethereal group on the solubility curve has been discussed.
Author Tadeusz Hofman (FC / DPC)
Tadeusz Hofman,,
- Department Of Physical Chemistry
, Mateusz Reda (FC / DPC)
Mateusz Reda,,
- Department Of Physical Chemistry
, Marek Gliński (FC / DCOC)
Marek Gliński,,
- Department Of Catalysis And Organometallic Chemistry
Journal seriesFluid Phase Equilibria, ISSN 0378-3812
Issue year2013
Vol356
Pages271-276
Publication size in sheets2.95
Keywords in EnglishLiquid–liquid equilibrium; Ether; Nitromethane; Group contribution; UNIFAC
ASJC Classification1606 Physical and Theoretical Chemistry; 3100 General Physics and Astronomy; 1500 General Chemical Engineering
DOIDOI:10.1016/j.fluid.2013.07.002
URL http://www.sciencedirect.com/science/article/pii/S0378381213003415
Languageen angielski
File
8-s2.0-S0378381213003415-main.pdf 590.78 KB
Score (nominal)30
Score sourcejournalList
ScoreMinisterial score = 30.0, 02-02-2020, ArticleFromJournal
Ministerial score (2013-2016) = 30.0, 02-02-2020, ArticleFromJournal
Publication indicators Scopus Citations = 8; WoS Citations = 6; Scopus SNIP (Source Normalised Impact per Paper): 2013 = 1.277; WoS Impact Factor: 2013 = 2.241 (2) - 2013=2.244 (5)
Citation count*1 (2015-02-24)
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