Core–shell structure of fly ash particles - SIMS depth profile analysis

P. Konarski , A. Zawada , Katarzyna Juda-Rezler , Dominik Kowalczyk

Abstract

Depth profile analysis in secondary ion mass spectrometry (SIMS) is applied for fly ash particles collected from three electrostatic precipitators in coal combustion type Thermoelectric Power Plant in Warsaw, Poland. Prior to analysis, particles of the collected material were size separated in nine stage cascade impactor with rotating substrate plates. Bulk analysis of the chosen size fractions was performed by atomic absorption spectroscopy. For SIMS depth profile analysis, particles were deposited on indium foils of high purity. Sputtering with 5 keV Ar+, 100 µm diameter ion beam was performed over 1.2 × 1.8 mm area of the indium foil in SIMS system (SAJW-05 model) equipped with Physical Electronics ion gun and QMA-410 Balzers quadrupole analyzer. SIMS data are quantified based on bulk concentration values of: carbon, sodium, aluminium, silicon, calcium, chromium, manganese, iron and nickel. Core–shell structure, and also cenosphere structure, is found. Depth profile analysis shows that shell layers of particles are enriched in carbon, calcium, chromium and nickel. Inner parts of particles or their cores are enriched in sodium and aluminium. Copyright © 2012 John Wiley \& Sons, Ltd.
Author P. Konarski - [Instytut Tele-i Radiotechniczny, Warszawa]
P. Konarski,,
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, A. Zawada - [Instytut Tele-i Radiotechniczny, Warszawa]
A. Zawada,,
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, Katarzyna Juda-Rezler (FEE / CEP)
Katarzyna Juda-Rezler,,
- Chair of Environmental Protection
, Dominik Kowalczyk (FEE)
Dominik Kowalczyk,,
- Faculty of Environmental Engineering
Journal seriesSurface and Interface Analysis, ISSN 0142-2421
Issue year2013
Vol45
No1
Pages592–595
Keywords in Englishcenosphere, coal combustion, core – shell structure, depth profile analysis, fly ash particles, SIMS
ASJC Classification2505 Materials Chemistry; 2508 Surfaces, Coatings and Films; 3110 Surfaces and Interfaces; 3104 Condensed Matter Physics; 1600 General Chemistry
DOIDOI:10.1002/sia.5143
URL http://onlinelibrary.wiley.com/doi/10.1002/sia.5143/abstract
Languageen angielski
Score (nominal)20
Score sourcejournalList
ScoreMinisterial score = 15.0, 14-01-2020, ArticleFromJournal
Ministerial score (2013-2016) = 20.0, 14-01-2020, ArticleFromJournal
Publication indicators Scopus Citations = 4; WoS Citations = 4; GS Citations = 2.0; Scopus SNIP (Source Normalised Impact per Paper): 2014 = 0.779; WoS Impact Factor: 2013 = 1.393 (2) - 2013=1.388 (5)
Citation count*2 (2015-01-30)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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