Covalently linked multi-calixarenes

O. Mogck , Paweł Parzuchowski , M. Nissinen , V. Böhmer , Gabriel Rokicki , K. Rissanen

Abstract

ipso-Nitration of t-butyl calix[4]arene tetraethers and subsequent hydrogenation provides an easy access to monoamino calix[4]arenes. Reaction with di- and triacid chlorides leads to various double- and triple-calix[4]arenes. With tetraacid chlorides derived from calix[4]arenes in the cone- or 1,3-alternate-conformations penta-calix[4]arenes are available as molecularly uniform species, which may be regarded as the first generation of calix[4]arene based dendrimers. The structure of the mononitro tetraester derivative, which may serve as a general building block has been confirmed by single crystal X-ray analysis.
Author O. Mogck
O. Mogck,,
-
, Paweł Parzuchowski KChTP
Paweł Parzuchowski,,
- Chair Of Polymer Chemistry And Technology
, M. Nissinen
M. Nissinen,,
-
, V. Böhmer
V. Böhmer,,
-
, Gabriel Rokicki KChTP
Gabriel Rokicki,,
- Chair Of Polymer Chemistry And Technology
, K. Rissanen
K. Rissanen,,
-
Journal seriesTetrahedron, ISSN 0040-4020
Issue year1998
Vol54
No34
Pages10053-10068
DOIDOI:10.1016/S0040-4020(98)00594-8
URL http://www.sciencedirect.com/science/article/pii/S0040402098005948
Score (nominal)30
Publication indicators WoS Impact Factor: 2006 = 2.817 (2) - 2007=2.854 (5)
Citation count*51 (2015-10-25)
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