Solubility of long-chain n-alkanols in dipropyl and dibutyl ether
J. Rolińska , E. Krumplewska , Tadeusz Hofman
AbstractSolubility of the following 1-alkanols (1-dodecanol, 1-tridecanol, 1-tetradecanol, 1-pentadecanol, 1-hexadecanol and 1-octadecanol) in dipropyl ether or dibutyl ether are reported. They have been measured by the dynamic method from a temperature close to 0°C up to the melting point. All systems exhibit positive deviations from ideal solubility. For all the alcohols, two transition points close to the melting temperature have been observed. The abilities of the Modified UNIFAC (Dortmund) and the DISQUAC models to predict these data have been tested.
|Journal series||Fluid Phase Equilibria, ISSN 0378-3812|
|Keywords in English||Data, mixture, Solid-liquid equilibrium|
|ASJC Classification||; ;|
|Publication indicators||= 5; : 1999 = 0.887; : 2006 = 1.68 (2) - 2007=1.621 (5)|
|Citation count*||5 (2015-04-08)|
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.