New phase equilibrium data at ambient and high pressure for strongly asymmetric mixtures containing menthol

Kamil Paduszyński , Mikołaj Więckowski , Marcin Okuniewski , Urszula Domańska-Żelazna


New data on phase equilibria in binary and ternary mixtures containing (−)-menthol, n-decane, 1-decanol and water are presented and discussed. In particular, experimental liquid-liquid equilibrium phase diagrams in ternary systems {(−)-menthol + (n-decane, or 1-decanol) + water} are reported along with the predictions by means of leading thermodynamic models, namely, perturbed-chain statistical associating fluid theory (PC-SAFT) and conductor-like screening model for real solvents (COSMO-RS). Freezing pressure data for binary systems {(−)-menthol + (n-decane, or 1-decanol)} are reported and the corresponding high-pressure solid-liquid equilibrium phase diagrams are discussed and analyzed by using the Yang equation. The measured data are referred to ambient-pressure phase diagrams published previously.
Author Kamil Paduszyński (FC / DPC)
Kamil Paduszyński,,
- Department Of Physical Chemistry
, Mikołaj Więckowski (FC / DPC)
Mikołaj Więckowski,,
- Department Of Physical Chemistry
, Marcin Okuniewski (FC / DPC)
Marcin Okuniewski,,
- Department Of Physical Chemistry
, Urszula Domańska-Żelazna - Instytut Chemii Przemysłowej im. prof. Ignacego Mościckiego
Urszula Domańska-Żelazna,,
Journal seriesJournal of Molecular Liquids, ISSN 0167-7322, (N/A 100 pkt)
Issue year2019
Publication size in sheets5540.95
Keywords in EnglishMentholPhase diagramsLiquid-liquid equilibriumHigh pressurePC-SAFTCOSMO-RS
ASJC Classification1606 Physical and Theoretical Chemistry
Languageen angielski
Score (nominal)100
Score sourcejournalList
ScoreMinisterial score = 100.0, 20-10-2019, ArticleFromJournal
Publication indicators Scopus Citations = 0; WoS Citations = 0; Scopus SNIP (Source Normalised Impact per Paper): 2016 = 1.212; WoS Impact Factor: 2017 = 4.513 (2) - 2017=3.929 (5)
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