Properties of the Gamma-Cyclodextrin/CL-20 System

Paweł Maksimowski , Tomasz Rumianowski

Abstract

Cyclodextrin (CD) is a cyclic compound with a spatial structure in the shape of a toroid. It is characterized by specific properties. The outer portion of the structure has hydrophilic properties, while the cavity of the toroid is hydrophobic. This enables cyclodextrin to form inclusion complexes with the enclosure of lipophilic molecules in the interior. This paper presents the results of attempts to form a complex of γ-CD/CL-20. This study determined unambiguously that a γ-CD with CL-20 complex in a mole ratio 1:1 is formed as a result of mixing of solutions of γ-CD and CL-20. This conclusion was corroborated by FTIR, 1H NMR, UV-Vis spectroscopic techniques and by measurement of the density of the complex obtained. The resulting complex of γ-CD/CL-20 is characterized by much lower sensitivity to friction and impact than CL-20 itself.
Author Paweł Maksimowski ZMW
Paweł Maksimowski,,
- Department Of High-Energetic Materials
, Tomasz Rumianowski ZMW
Tomasz Rumianowski,,
- Department Of High-Energetic Materials
Journal seriesCentral European Journal of Energetic Materials, ISSN 1733-7178
Issue year2016
Vol13
No1
Pages217-229
Publication size in sheets0.6
Keywords in EnglishCL-20/γ-CD complex preparation, properties of CL-20/γ-CD complex, cyclodextrin, 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane, CL-20
URL http://www.wydawnictwa.ipo.waw.pl/CEJEM/contents.html
Languageen angielski
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Maksimowski.pdf (file archived - login or check accessibility on faculty) Maksimowski.pdf 517.71 KB
Score (nominal)30
ScoreMinisterial score = 25.0, 28-11-2017, ArticleFromJournal
Ministerial score (2013-2016) = 30.0, 28-11-2017, ArticleFromJournal
Publication indicators WoS Impact Factor: 2016 = 1.041 (2) - 2016=1.403 (5)
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