Raman scattering in BIMEVOX (ME=Mg, Ni, Cu, Zn) single crystals

Rajmund Bacewicz , Piotr Kurek

Abstract

The Raman spectra of BIMEVOX (ME=Mg, Ni, Cu, Zn) single crystals are reported. The main features of the spectra observed in the 600 to 900 cm−1 frequency range are assigned to the stretching vibrations of the V–O bonds. Interpretation of the Raman spectra is based on the diatomic approximation and the correlation between the frequencies of stretching vibrations of vanadium–oxygen bonds and bond lengths. V–O bond orders are determined from an empirical relation between these frequencies and bond orders. The results point to predominantly tetrahedral coordination of vanadium in the studied BIMEVOX systems.
Author Rajmund Bacewicz (FP / SD)
Rajmund Bacewicz,,
- Semiconductors Division
, Piotr Kurek (FP / SSID)
Piotr Kurek,,
- Solid State Ionics Division
Journal seriesSolid State Ionics, ISSN 0167-2738
Issue year2000
Vol127
No1–2
Pages151-156
Keywords in EnglishBIMEVOX, Crystal structure, Raman scattering, Vanadium compounds
ASJC Classification3104 Condensed Matter Physics; 2500 General Materials Science; 1600 General Chemistry
DOIDOI:10.1016/S0167-2738(99)00262-3
URL http://www.sciencedirect.com/science/article/pii/S0167273899002623
Languageen angielski
Score (nominal)35
Score sourcejournalList
Publication indicators WoS Citations = 9; Scopus Citations = 10; GS Citations = 3.0; Scopus SNIP (Source Normalised Impact per Paper): 2000 = 1.312; WoS Impact Factor: 2006 = 2.19 (2) - 2007=2.228 (5)
Citation count*3 (2016-01-24)
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