AC conductivity studies of composite polymeric electrolytes

Maciej Siekierski , Władysław Wieczorek , J. Przyłuski

Abstract

Ac conductivity studies carried out over a temperature range of 0–100°C for polymeric electrolytes from the PEO-LiClO4-α-Al2O3 system are reported. Electrolytes of various salt concentrations and containing 15 mass\% α-Al2O3 are studied. The contribution of charge carrier concentration and ion mobility to the dc ionic conductivity of these composite polymeric electrolytes is discussed. A change in the temperature dependence of ionic conductivity is observed around the melting point of the crystalline phase of the composite electrolytes. An increase in dielectric constant following this phase transition is also observed. Above the melting temperature, an increase in the conductivity depends either on an increase in ionic mobility (samples with low salt concentration) or on the creation of charge carriers (samples with high salt concentration).
Author Maciej Siekierski KChNTCS
Maciej Siekierski,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Władysław Wieczorek KChNTCS
Władysław Wieczorek,,
- Chair Of Inorganic Chemistry And Solid State Technology
, J. Przyłuski
J. Przyłuski,,
-
Journal seriesElectrochimica Acta, ISSN 0013-4686
Issue year1998
Vol43
No10–11
Pages1339-1342
Keywords in EnglishAc conductivity, Activation energy, charge carrier creation, ion mobility, melting temperature
DOIDOI:10.1016/S0013-4686(97)10040-8
URL http://www.sciencedirect.com/science/article/pii/S0013468697100408
Score (nominal)35
Publication indicators WoS Impact Factor: 2006 = 2.955 (2) - 2007=3.326 (5)
Citation count*39 (2015-03-10)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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