Thermodynamics and activity coefficients at infinite dilution measurements for organic solutes and water in the ionic liquid 1-butyl-1-methylpyrrolidinium tetracyanoborate

Urszula Domańska-Żelazna , Marek Królikowski , William E. Acree Jr.

Abstract

The activity coefficients at infinite dilution, γ 13 ∞ , for 45 solutes, including alkanes, cycloalkanes, alkenes, alkynes, aromatic hydrocarbons, alcohols, thiophene, tetrahydrofuran, ethers, acetone, and water, in the ionic liquid 1-butyl-1-methylpyrrolidinium tetracyanoborate, [BMPYR][TCB], were determined by gas–liquid chromatography at temperatures from 318.15 K to 368.15 K. The values of the partial molar excess Gibbs free energy Δ G 1 E, ∞ , enthalpy Δ H 1 E, ∞ , and entropy Δ S 1 E, ∞ at infinite dilution were calculated from the experimental γ 13 ∞ values obtained over the temperature range. The gas–liquid partition coefficients, KL were calculated for all solutes and the Abraham solvation parameter model was discussed. The values of the selectivity for different separation problems were calculated from γ 13 ∞ and compared to literature values for N-methyl-2-pyrrolidinone (NMP), sulfolane, 1-ethyl-3-methylimidazolium tetracyanoborate, [EMIM][TCB], 1-decyl-3-methylimidazolium tetracyanoborate, [DMIM][TCB], and similar ionic liquids. The densities of [BMPYR][TCB] in temperatures range from 318.15 K to 368.15 K, the temperature of fusion and the enthalpy of fusion were measured.
Author Urszula Domańska-Żelazna ZChF
Urszula Domańska-Żelazna,,
- Department Of Physical Chemistry
, Marek Królikowski ZChF
Marek Królikowski,,
- Department Of Physical Chemistry
, William E. Acree Jr.
William E. Acree Jr.,,
-
Journal seriesJournal of Chemical Thermodynamics, ISSN 0021-9614
Issue year2011
Vol43
No12
Pages1810-1817
Keywords in EnglishActivity coefficients at infinite dilution, [BMPYR][TCB], Density, The Abraham solvation parameter model, Thermodynamics
DOIDOI:10.1016/j.jct.2011.06.007
URL http://www.sciencedirect.com/science/article/pii/S0021961411002175
Languageen angielski
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Score (nominal)35
Publication indicators WoS Impact Factor: 2011 = 2.422 (2) - 2011=2.173 (5)
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