Investigation of new potential amine activa-tors for carbon dioxide absorption in carbonate solutions

Grzegorz Bińczak , Ryszard Pohorecki , Władysław Moniuk , Cezary Możeński

Abstract

Results of an extensive research program, aimed at finding new, more efficient activators of carbon dioxide absorption into aqueous carbonate/bicarbonate solutions are presented. Both single amines (2-ethyl-aminoethanol, 2-isopropyl aminoethanol, piperazine, tetraethylenepentamine, N-ethyl-piperazine and glicyne) and amine mixtures have been investigated. Absorption rate measurements were conducted in a laminar-jet absorber. Reaction rate constants for the particular activators were determined.Mixtures of aliphatic amines with cyclic amines, as well as mixtures of cyclic amines with cyclic amines were found to exhibit synergetic effect. Such amine mixtures might be used as new promoters for CO2 absorption in carbonate solutions in the modified Benfield process.
Author Grzegorz Bińczak - Instytut Nowych Syntez Chemicznych
Grzegorz Bińczak,,
-
, Ryszard Pohorecki (FCPE)
Ryszard Pohorecki,,
- Faculty of Chemical and Process Engineering
, Władysław Moniuk (FCPE / DBBE)
Władysław Moniuk,,
- Department of Biotechnology and Bioprocess Engineering
, Cezary Możeński
Cezary Możeński,,
-
Journal seriesChemical and Process Engineering [Inżynieria Chemiczna i Procesowa], ISSN 0208-6425, (A 15 pkt)
Issue year2018
Vol39
No4
Pages353-365
Publication size in sheets0.6
Keywords in Englishcarbon dioxide, absorption, potassium carbonates, amine activators, laminar jet
ASJC Classification1500 General Chemical Engineering; 1600 General Chemistry
DOIDOI:10.24425/122956
URL http://journals.pan.pl/dlibra/publication/122956/edition/107197/content/investigation-of-new-potential-amine-activa-tors-for-carbon-dioxide-absorption-in-carbonate-solutions-binczak-grzegorz-pohorecki-ryszard-moniuk-wladyslaw-mozenski-cezary?language=en
Languageen angielski
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Score (nominal)15
ScoreMinisterial score = 15.0, 22-01-2019, ArticleFromJournal
Ministerial score (2013-2016) = 15.0, 22-01-2019, ArticleFromJournal
Publication indicators Scopus SNIP (Source Normalised Impact per Paper): 2017 = 0.701; WoS Impact Factor: 2017 = 0.892 (2) - 2017=0.894 (5)
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