The cyclopentadienylaluminium etheralkoxide derivative [(η1-C5H5)2Al(μ-OCH2CH2O-nPr)]2; synthesis and structure
Sławomir Szumacher , Izabela Madura , Janusz Zachara , Antoni Kunicki
AbstractThe reaction of [Cl2Al(μ-OCH2CH2O-nPr)]2 (1) with NaCp leads to the formation of etheralkoxy bridged dimer [(η1-C5H5)2Al(μ-OCH2CH2O-nPr)]2 (2) containing five-coordinate aluminium atoms. The compound was characterised by 1H-, 13C- and 27Al-NMR spectra and its crystal structure was determined by single crystal X-ray diffraction studies.
|Journal series||Journal of Organometallic Chemistry, ISSN 0022-328X|
|Keywords in English||2-Propoxyethanol, aluminium, Bifunctional, Cyclopentadienyl|
|ASJC Classification||; ; ; ;|
|Publication indicators||= 9; = 8; = 10.0; : 2000 = 0.78; : 2006 = 2.332 (2) - 2007=2.097 (5)|
|Citation count*||10 (2015-05-11)|
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.