Measurements, Correlations, and Mod. UNIFAC (Do) Prediction of (Solid−Liquid) Phase Equilibria Diagrams in Binary Systems (Aliphatic Ketone + an Alcohol)

Urszula Domańska-Żelazna , Kamil Paduszyński , Joanna Da̧bska

Abstract

The (solid?liquid) phase equilibria (SLE) of binary mixtures containing fragrance raw materials \heptan-2-one, or nonan-2-one, or undecan-2-one, or dodecan-2-one, or tridecan-2-one + octan-1-ol, or decan-1-ol, or dodecan-1-ol\ were investigated. These systems have been measured by a dynamic method over a wide temperature range from (230 to 300) K and ambient pressure. All binary systems revealed simple eutectic mixtures with complete miscibility in the liquid phase. The experimental data were correlated by the UNIQUAC, NRTL, and Wilson equations, utilizing parameters derived from the SLE. The standard deviations of the solubility temperatures were (0.52, 0.52, and 0.46) K for the UNIQUAC, NRTL, and Wilson equations, respectively. The Mod. UNIFAC (Do) representation of the SLE with known, literature parameters has given very good results.
Author Urszula Domańska-Żelazna ZChF
Urszula Domańska-Żelazna,,
- Department Of Physical Chemistry
, Kamil Paduszyński ZChF
Kamil Paduszyński,,
- Department Of Physical Chemistry
, Joanna Da̧bska
Joanna Da̧bska,,
-
Journal seriesJournal of Chemical and Engineering Data, ISSN 0021-9568
Issue year2011
Vol56
No4
Pages881-888
DOIDOI:10.1021/je100725a
URL http://dx.doi.org/10.1021/je100725a
Languageen angielski
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je100725a.pdf 937.71 KB
Score (nominal)35
Publication indicators WoS Impact Factor [Impact Factor WoS]: 2011 = 1.693 (2) - 2011=1.965 (5)
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