Mixed conductivity in poly(p-phenylene) doped with iron chloride

Janusz Płocharski , Henryk Wyciślik

Abstract

Poly(p-phenylene) is a conjugated polymer that becomes conductive after doping. It has been demonstrated that the amorphous polymer lightly doped with iron(III) chloride exhibits both electronic and ionic conductivity in the range 10−8–10−5 S/cm. Annealing the pristine amorphous polymer and doping it to the same level leads to a partially crystalline material, the exclusively electronic conductivity of which is one order of magnitude higher. The relative dielectric constant, however, seems to be unaffected by the polymer structure. The temperature dependencies of both components of the conductivity were measured giving similar values of activation energies within the range 0.29–0.36 eV.
Author Janusz Płocharski (FC / CICSST)
Janusz Płocharski,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Henryk Wyciślik
Henryk Wyciślik,,
-
Journal seriesSolid State Ionics, ISSN 0167-2738
Issue year2000
Vol127
No3–4
Pages337-344
Keywords in EnglishConjugated polymer, Ionic conductivity, Mixed-type conductivity, Poly(p-phenylene), Temperature dependence of conductivity, Temperature dependence of relative dielectric constant
ASJC Classification3104 Condensed Matter Physics; 2500 General Materials Science; 1600 General Chemistry
DOIDOI:10.1016/S0167-2738(99)00284-2
URL http://www.sciencedirect.com/science/article/pii/S0167273899002842
Score (nominal)35
Publication indicators Scopus SNIP (Source Normalised Impact per Paper): 2000 = 1.312; WoS Impact Factor: 2006 = 2.19 (2) - 2007=2.228 (5)
Citation count*18 (2015-08-25)
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