Synthesis of lutetium(iii)-porphyrin complexes: old problems and new excellent conditions found

Bartosz Kalota , Agnieszka Mikus , Stanisław Ostrowski

Abstract

A convenient method for the preparation of very attractive and almost unknown lutetium(iii)-porphyrins was developed. Systematic investigations involving a broad spectrum of solvents (DMF, TCB, imidazole, sulfolane, and a CHCl3/MeOH mixture), as well as studies concerning the influence of temperature and the reaction time on the yield, were performed. Under the optimized experimental conditions found within the study for [5,10,15,20-tetraphenylporphyrinato]lutetium(iii) chloride (sulfolane, reflux, 0.5 h; 88% yield), the synthesis of some other more complex derivatives was demonstrated.

Author Bartosz Kalota - [Akademia im. Jana Dlugosza w Czestochowie]
Bartosz Kalota,,
-
-
, Agnieszka Mikus - [Uniwersytet Przyrodniczo-Humanistyczny w Siedlcach]
Agnieszka Mikus,,
-
- Uniwersytet Przyrodniczo-Humanistyczny w Siedlcach
, Stanisław Ostrowski (FC / DOC)
Stanisław Ostrowski,,
- Department Of Organic Chemistry
Journal seriesNew Journal of Chemistry, ISSN 1144-0546, (A 30 pkt)
Issue year2016
Vol40
Pages9899-9902
ASJC Classification2505 Materials Chemistry; 1600 General Chemistry; 1503 Catalysis
DOIDOI:10.1039/c6nj02424f
Languageen angielski
Score (nominal)30
ScoreMinisterial score = 30.0, 05-09-2019, ArticleFromJournal
Ministerial score (2013-2016) = 30.0, 05-09-2019, ArticleFromJournal
Publication indicators Scopus Citations = 0; WoS Citations = 0; Scopus SNIP (Source Normalised Impact per Paper): 2016 = 0.766; WoS Impact Factor: 2016 = 3.269 (2) - 2016=3.103 (5)
Citation count*
Cite
Share Share

Get link to the record


* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
Back
Confirmation
Are you sure?