Synthesis of lutetium(iii)-porphyrin complexes: old problems and new excellent conditions found
Bartosz Kalota , Agnieszka Mikus , Stanisław Ostrowski
A convenient method for the preparation of very attractive and almost unknown lutetium(iii)-porphyrins was developed. Systematic investigations involving a broad spectrum of solvents (DMF, TCB, imidazole, sulfolane, and a CHCl3/MeOH mixture), as well as studies concerning the influence of temperature and the reaction time on the yield, were performed. Under the optimized experimental conditions found within the study for [5,10,15,20-tetraphenylporphyrinato]lutetium(iii) chloride (sulfolane, reflux, 0.5 h; 88% yield), the synthesis of some other more complex derivatives was demonstrated.
|Journal series||New Journal of Chemistry, ISSN 1144-0546, (A 30 pkt)|
|ASJC Classification||; ;|
|Score|| = 30.0, 05-09-2019, ArticleFromJournal|
= 30.0, 05-09-2019, ArticleFromJournal
|Publication indicators||= 0; = 0; : 2016 = 0.766; : 2016 = 3.269 (2) - 2016=3.103 (5)|
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.