Highly Conducting Lithium Polyelectrolytes Based on Maleic Anhydride−Styrene Copolymers

Zbigniew Florjańczyk , Wojciech Bzducha , Władysław Wieczorek , Ewa Zygadło-Monikowska , Włodzimierz Krawiec , Song H. Chung

Abstract

Comblike polyelectrolytes comprising immobilized carboxylic anions and poly(oxyethylene) (OCH2CH2)n side chains of various length were obtained from the reaction of appropriate lithium alcoholates with maleic anhydride?styrene alternating copolymers. These materials may be fabricated as films of ambient temperature conductivity in the range of 10-9?10-6 S·cm-1, depending on the side-chain length. The conductivity values increase by 2?3 orders of magnitude after the addition of strong polar plasticizers such as dimethyl sulfoxide and propylene carbonate. A further increase in conductivity was observed after the complexation of carboxylic anions by BF3. On the basis of 13C NMR studies and 7Li NMR relaxation times of lithium carboxylates, it was found that the anion complexing agent reduces ion pairing in polyelectrolytes more effectively than cation-solvating solvents. The possible conduction mechanism in the solid and gel polyelectrolytes is discussed.
Author Zbigniew Florjańczyk KChTP
Zbigniew Florjańczyk,,
- Chair Of Polymer Chemistry And Technology
, Wojciech Bzducha
Wojciech Bzducha,,
-
, Władysław Wieczorek KChNTCS
Władysław Wieczorek,,
- Chair Of Inorganic Chemistry And Solid State Technology
, Ewa Zygadło-Monikowska KChTP
Ewa Zygadło-Monikowska,,
- Chair Of Polymer Chemistry And Technology
, Włodzimierz Krawiec
Włodzimierz Krawiec,,
-
, Song H. Chung
Song H. Chung,,
-
Journal seriesJournal of Physical Chemistry B, ISSN 1520-6106
Issue year1998
Vol102
No43
Pages8409-8416
DOIDOI:10.1021/jp982120n
URL http://dx.doi.org/10.1021/jp982120n
Score (nominal)35
Publication indicators WoS Impact Factor: 2006 = 4.115 (2) - 2007=4.475 (5)
Citation count*20 (2016-02-26)
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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