Catalytic Ketonization over Oxide Catalysts, Part IV. Cycloketonization of Diethyl Hexanodiate

Marek Gliński , Michał Kaszubski

Abstract

Activity of 20 wt.\% MO2/S catalysts, where M = Mn, Ce and Th, and S = Al2O3 or SiO2, has been studied in cycloketonization of diethyl hexanodiate at the temperature range 573-698 K in a flow system. Only moderate yields of cyclopentanone (\\textless\35\%) were achieved. The highest yields of ketone were obtained over MnO2/Al2O3 and MnO2/SiO2 catalysts - 33 and 27\%, respectively. ThO2 containing catalysts were the most active, whereby ester transformations were detected below 573 K. In the presence of all catalysts the formation of the main product was accompanied by various amounts of 2-ethylcyclopentanone, cyclopent-2-en-1-one, cyclopentene, 2-cyclopentylidenecyclopentanone and numerous unidentified by-products.
Author Marek Gliński (FC / DCOC)
Marek Gliński,,
- Department Of Catalysis And Organometallic Chemistry
, Michał Kaszubski
Michał Kaszubski,,
-
Journal seriesReaction Kinetics and Catalysis Letters, ISSN 0133-1736, 1588-2837
Issue year2000
Vol70
No2
Pages271-274
Keywords in Englishcyclopentanone, diethyl adipate, Industrial Chemistry/Chemical Engineering, ketonization of esters, manganese and cerium oxide catalysts, Physical Chemistry
DOIDOI:10.1023/A:1010332714901
URL http://link.springer.com/article/10.1023/A%3A1010332714901
Score (nominal)0
Score sourcejournalList
Publication indicators WoS Citations = 17
Citation count*13 (2015-02-24)
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